Thermoplastic vulcanizate (TPV) has excellent elastomeric properties and can be reprocessed multiple times. TPV is typically produced by using the dynamic vulcanization (DV) method in which rubber is crosslinked simultaneously with thermoplastics. Peroxide-crosslinked TPV can increase the compatibility between rubber and thermoplastics but loses its reprocessability due to excess crosslinking in the latter. In this work, we overcome this obstacle by using a two-step mixing method to prepare fully crosslinked elastomers of ethylene vinyl acetate copolymer (EVA) and natural rubber (NR). Each sample formulation was prepared with three different mixing methods for comparison: NR-DV, Split-DV, and All-DV. For NR-DV, NR was crosslinked prior to the addition of EVA together with the thermal stabilizer (TS). For Split-DV, a small amount of EVA and NR was crosslinked prior to the addition of EVA and TS. In the All-DV method, EVA and NR were crosslinked, and then TS was added. The appearance and processability of the samples were affected by the degree of crosslinking. NR-DV showed a non-homogeneous texture. Although the samples of the All-DV method appeared homogeneous, their mechanical and rheological properties were inferior to those of the Split-DV method. The mechanical properties of the Split-DV samples were not significantly changed after reprocessing 10 times. Therefore, Split-DV is the preferred method for TPV production.
The application of the synergistic effect between the crystal structure of poly(lactic acid) (PLA) and the presence of ethylene vinyl acetate copolymer (EVA) to produce highly ductile PLA/EVA blends
