Correlation Studies Between Structural and Ionic Transport Properties of Lithium-Ion Hybrid Gel Polymer Electrolytes Based PMMA-PLA

2021 ◽  
Author(s):  
N. F. Mazuki ◽  
M. Z. Kufian ◽  
Y. Nagao ◽  
A. S. Samsudin
Keyword(s):  
Transport Properties ◽  
Polymer Electrolytes ◽  
Lithium Ion ◽  
Ionic Transport ◽  
Gel Polymer Electrolytes ◽  
Correlation Studies ◽  
Hybrid Gel

scholarly journals Correlation Between Structural and Ionic Transport Properties of Lithium-ion Hybrid Gel Polymer Electrolytes Based PMMA-PLA

2021 ◽  
Author(s):  
Norfatihah Mazuki ◽  
M.Z. Kufian ◽  
Y. Nagao ◽  
Ahmad Salihin Samsudin
Keyword(s):  
Ionic Conductivity ◽  
Transport Properties ◽  
Polymer Electrolytes ◽  
Ionic Conduction ◽  
Lithium Ion ◽  
Cole Plot ◽  
Gel Polymer Electrolytes ◽  
Hybrid Polymer ◽  
Good Thermal Stability ◽  
Hybrid Gel

Abstract In this work, the investigation on hybrid gel polymer electrolytes (HGPEs) comprising polymethyl methacrylate (PMMA)-polylactic acid (PLA) incorporate with LiTFSI were carried out. The HGPEs samples were characterized for their structural, thermal and ionic conduction properties via FTIR, XRD, DSC, and EIS. FTIR analysis show the indication of the interaction between PMMA-PLA hybrid polymer and LiTFSI with the appearance of peak and changes in peak shifting at the coordinating site from polymer blend. The DSC analysis shows that the glass transition temperature (Tg) of HGPEs was decreased as the LiTFSI content increases, suggesting that the HGPEs system has good thermal stability. The ionic conductivity was calculated based on the Cole-Cole plot and the incorporation of LiTFSI with 20 wt. % into hybrid polymer matrixes revealed the maximum ionic conductivity of 1.02 х 10-3 S cm-1 at room temperature as the amorphous phase increases. The dissociation of ions and transport properties of the PMMA-PLA-LiTFSI systems was determined via dielectric response approach and it was found that number density (ɳ), mobility (μ), and diffusion coefficient (D) of mobile ions follows ionic conductivity trend.

Polyethylene Glycol-Functionalized Siloxane Hybrid Gel Polymer Electrolytes for Lithium Ion Batteries

2017 ◽  
Vol 17 (5) ◽  
pp. 3016-3020 ◽  
Author(s):  
Albert S Lee ◽  
Jin Hong Lee ◽  
Jong-Chan Lee ◽  
Soon Man Hong ◽  
Seung Sang Hwang ◽  
...  
Keyword(s):  
Polyethylene Glycol ◽  
Lithium Ion Batteries ◽  
Polymer Electrolytes ◽  
Lithium Ion ◽  
Gel Polymer Electrolytes ◽  
Hybrid Gel

Lithium ion conduction and ion–polymer interaction in PVdF-HFP based gel polymer electrolytes

2014 ◽  
Vol 268 ◽  
pp. 288-293 ◽  
Author(s):  
K.B.Md. Isa ◽  
Z. Osman ◽  
A.K. Arof ◽  
L. Othman ◽  
N.H. Zainol ◽  
...  
Keyword(s):  
Polymer Electrolytes ◽  
Lithium Ion ◽  
Gel Polymer Electrolytes ◽  
Ion Conduction ◽  
Lithium Ion Conduction ◽  
Polymer Interaction

Immobilized cation functional gel polymer electrolytes with high lithium transference number for lithium ion batteries

2019 ◽  
Vol 572 ◽  
pp. 382-389 ◽  
Author(s):  
Chih-Hao Tsao ◽  
Hou-Ming Su ◽  
Hsiang-Ting Huang ◽  
Ping-Lin Kuo ◽  
Hsisheng Teng
Keyword(s):  
Lithium Ion Batteries ◽  
Polymer Electrolytes ◽  
Lithium Ion ◽  
Transference Number ◽  
Gel Polymer Electrolytes
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