Regio- and stereoselective reaction of sodium benzeneselenolate with 3-(trimethylsilyl)prop-2-ynamides

2019 ◽  
Vol 68 (11) ◽  
pp. 2134-2136 ◽  
Author(s):  
M. V. Andreev ◽  
V. A. Potapov ◽  
M. V. Musalov ◽  
L. I. Larina ◽  
S. V. Amosova
Keyword(s):  
Stereoselective Reaction

scholarly journals (2Sp,4R,8Sp)-4-Methyl-1-phenyl-diferroceno-5-Z-ethylene-1-phosphinoxide

Molbank ◽  
10.3390/m1105 ◽  
2020 ◽  
Vol 2020 (1) ◽  
pp. M1105 ◽  
Author(s):  
Philipp Honegger ◽  
Michael Widhalm
Keyword(s):  
Reaction Mechanism ◽  
Asymmetric Catalysis ◽  
Title Compound ◽  
Compound A ◽  
Stereoselective Reaction

We present a synthesis of the title compound, a homochiral diferroceno cycle intended for use in asymmetric catalysis. We present a hydrovinylation protocol, which allows the production of the title compound in two steps from a known diferrocenyl precursor. We obtained one of two possible diastereomers selectively and propose a plausible regio- and stereoselective reaction mechanism.

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