Syntheses and crystal structures of ruthenium carbonyl complexes containing pyridine-alkoxide ligands

2019 ◽  
Vol 45 (2) ◽  
pp. 83-90
Author(s):  
Zhi-Qiang Hao ◽  
Si-Qi Zong ◽  
Xin-Long Yan ◽  
Zhi-Hong Ma ◽  
Su-Zhen Li ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Carbonyl Complexes ◽  
Ruthenium Carbonyl ◽  
Alkoxide Ligands

Ruthenium carbonyl complexes bearing bidentate pyridine-alkoxide ligands: Synthesis, crystal structures and reactivity

2019 ◽  
Vol 484 ◽  
pp. 142-147 ◽  
Author(s):  
Zhihong Ma ◽  
Qian Liu ◽  
Suzhen Li ◽  
Ruitao Wu ◽  
Zhangang Han ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Carbonyl Complexes ◽  
Ruthenium Carbonyl ◽  
Alkoxide Ligands

Ruthenium carbonyl complexes supported by pyridine-alkoxide ligands: synthesis, structure and catalytic oxidation of secondary alcohols

2019 ◽  
Vol 43 (35) ◽  
pp. 13947-13953 ◽  
Author(s):  
Siqi Zong ◽  
Kang Liu ◽  
Xiaohui Yue ◽  
Zhiqiang Hao ◽  
Zhihong Ma ◽  
...  
Keyword(s):  
Catalytic Oxidation ◽  
Secondary Alcohols ◽  
Carbonyl Complexes ◽  
Ruthenium Carbonyl ◽  
Alkoxide Ligands

Five novel trinuclear ruthenium carbonyl complexes were synthesized and their application in oxidation of secondary alcohols was also researched.

Ruthenium carbonyl complexes with pyridine-alkoxide ligands: synthesis, characterization and catalytic application in dehydrogenative oxidation of alcohols

2018 ◽  
Vol 42 (18) ◽  
pp. 15472-15478 ◽  
Author(s):  
Zhiqiang Hao ◽  
Xinlong Yan ◽  
Kang Liu ◽  
Xiaohui Yue ◽  
Zhangang Han ◽  
...  
Keyword(s):  
Secondary Alcohols ◽  
Carbonyl Complexes ◽  
Mild Conditions ◽  
Catalytic Application ◽  
Ruthenium Carbonyl ◽  
Oxidation Of Alcohols ◽  
Alkoxide Ligands

Dehydrogenative oxidation of secondary alcohols catalyzed by several new trinuclear ruthenium carbonyl complexes under mild conditions was proposed.

Ruthenium carbonyl complexes. III. Peparations, properties and structures of Dicarbonyl- and Monocarbonyl-(2,2':6',2''-terpyridyl)ruthenium(II) complexes

1984 ◽  
Vol 37 (5) ◽  
pp. 929 ◽  
Author(s):  
GB Deacon ◽  
JM Patrick ◽  
BW Skelton ◽  
NC Thomas ◽  
AH White
Keyword(s):  
Crystal Structure ◽  
Crystal Structures ◽  
Room Temperature ◽  
Chloro Complex ◽  
Carbonyl Complexes ◽  
X Ray ◽  
X Ray Crystallography ◽  
Ruthenium Carbonyl

Reaction of 2,2':6',2''-terpyridyl (tpy) with ruthenium dicarbonyl dihalides yields the complexes Ru(CO)2X2(tpy) (X = Br or Cl), which can be protonated giving [Ru(CO)2X2(tpyH)]ClO4. Crystal structures of the two forms (red and yellow) of Ru(CO)2Br2(tpy) show each to have octahedral stereo-chemistry with cis-carbonyls, trans-bromines, and bidentate tpy. Treatment of Ru(CO)2X2(tpy) complexes with trimethylamine N-oxide in dichloromethane at room temperature gives cis-Ru(CO)X2(tpy) complexes. The presence of cis halogens and tridentate terpyridyl in the chloro complex has been established by X-ray crystallography. Reaction of terpyridyl with ruthenium trichloride in dimethylformamide yields trans-Ru(CO)Cl2(tpy), the crystal structure of which has been determined.

Sign in / Sign up

Export Citation Format

Share Document