Structure-property relationships in ILs: A study of the alkyl chain length dependence in vaporisation enthalpies of pyridinium based ionic liquids

2012 ◽  
Vol 55 (8) ◽  
pp. 1525-1531 ◽  
Author(s):  
Dzmitry H. Zaitsau ◽  
Andrei V. Yermalayeu ◽  
Vladimir N. Emel’yanenko ◽  
Sergey P. Verevkin ◽  
Urs Welz-Biermann ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Chain Length ◽  
Alkyl Chain ◽  
Alkyl Chain Length ◽  
Structure Property ◽  
Length Dependence ◽  
Structure Property Relationships

Does alkyl chain length really matter? Structure–property relationships in thermochemistry of ionic liquids

2013 ◽  
Vol 562 ◽  
pp. 84-95 ◽  
Author(s):  
Sergey P. Verevkin ◽  
Dzmitry H. Zaitsau ◽  
Vladimir N. Emel’yanenko ◽  
Ricardas V. Ralys ◽  
Andrei V. Yermalayeu ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Chain Length ◽  
Alkyl Chain ◽  
Alkyl Chain Length ◽  
Structure Property ◽  
Structure Property Relationships

Vaporization enthalpies of imidazolium based ionic liquids. A thermogravimetric study of the alkyl chain length dependence

2012 ◽  
Vol 54 ◽  
pp. 433-437 ◽  
Author(s):  
Sergey P. Verevkin ◽  
Dzmitry H. Zaitsau ◽  
Vladimir N. Emel’yanenko ◽  
Ricardas V. Ralys ◽  
Andrei V. Yermalayeu ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Chain Length ◽  
Alkyl Chain ◽  
Alkyl Chain Length ◽  
Thermogravimetric Study ◽  
Length Dependence

Building Blocks for Ionic Liquids: A Study of Alkyl Chain Length Dependence of Vaporization Enthalpies of 1-(n-Alkyl)-2-methylimidazoles

2011 ◽  
Vol 56 (9) ◽  
pp. 3532-3540 ◽  
Author(s):  
Vladimir N. Emel'yanenko ◽  
Svetlana V. Portnova ◽  
Sergey P. Verevkin ◽  
Andrzej Skrzypczak
Keyword(s):  
Ionic Liquids ◽  
Chain Length ◽  
Alkyl Chain ◽  
Building Blocks ◽  
Alkyl Chain Length ◽  
Length Dependence

scholarly journals Influence of Alkyl Chain Length on Thermal Properties, Structure, and Self-Diffusion Coefficients of Alkyltriethylammonium-Based Ionic Liquids

2021 ◽  
Vol 22 (11) ◽  
pp. 5935
Author(s):  
Roksana Markiewicz ◽  
Adam Klimaszyk ◽  
Marcin Jarek ◽  
Michał Taube ◽  
Patryk Florczak ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Chain Length ◽  
Diffusion Coefficients ◽  
Alkyl Chain ◽  
Alkyl Chain Length ◽  
Chain Elongation ◽  
Polar Regions ◽  
Structure Property ◽  
Separation Science ◽  
Self Diffusion

The application of ionic liquids (ILs) has grown enormously, from their use as simple solvents, catalysts, media in separation science, or electrolytes to that as task-specific, tunable molecular machines with appropriate properties. A thorough understanding of these properties and structure–property relationships is needed to fully exploit their potential, open new directions in IL-based research and, finally, properly implement the appropriate applications. In this work, we investigated the structure–properties relationships of a series of alkyltriethylammonium bis(trifluoromethanesulfonyl)imide [TEA-R][TFSI] ionic liquids in relation to their thermal behavior, structure organization, and self-diffusion coefficients in the bulk state using DSC, FT-IR, SAXS, and NMR diffusometry techniques. The phase transition temperatures were determined, indicating alkyl chain dependency. Fourier-transformed infrared spectroscopy studies revealed the structuration of the ionic liquids along with alkyl chain elongation. SAXS experiments clearly demonstrated the existence of polar/non-polar domains. The alkyl chain length influenced the expansion of the non-polar domains, leading to the expansion between cation heads in polar regions of the structured IL. 1H NMR self-diffusion coefficients indicated that alkyl chain elongation generally caused the lowering of the self-diffusion coefficients. Moreover, we show that the diffusion of anions and cations of ILs is similar, even though they vary in their size.

Spectroscopic Study on Imidazolium-Based Ionic Liquids: Effect of Alkyl Chain Length and Anion

2012 ◽  
Vol 116 (11) ◽  
pp. 3512-3518 ◽  
Author(s):  
Enrico Binetti ◽  
Annamaria Panniello ◽  
Leonardo Triggiani ◽  
Raffaele Tommasi ◽  
Angela Agostiano ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Spectroscopic Study ◽  
Chain Length ◽  
Alkyl Chain ◽  
Alkyl Chain Length
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