Alloying Element Partition and Growth Kinetics of Proeutectoid Ferrite in Hot-Deformed Fe-0.1C-3Mn-1.5Si Austenite

2011 ◽  
Vol 42 (8) ◽  
pp. 2189-2198 ◽  
Author(s):  
R. Wei ◽  
K. Kanno ◽  
M. Enomoto
2021 ◽  
Vol ahead-of-print (ahead-of-print) ◽  
Author(s):  
Chung-Yung Lin

Purpose This paper aims to derive a model of growth kinetics of the intermetallic compound (IMC) layer formed in the reaction between liquid Sn-based solders and Ni particle reinforcements and to compare with the experimental data to verify the effects of Sn concentration and alloying element. Design/methodology/approach A composite solder was manufactured by mechanically introducing Ni particle reinforcements into a solder matrix. The effect of the non-reactive alloying elements, Ag, Pb and Bi, on the growth kinetics of the IMC formed between liquid Sn-based eutectic solders and Ni particles, reacting this composite solder at 250°C–280°C was studied. Findings Experimental results showed that only the IMC Ni3Sn4 was present as a reaction product. Using the diffusion-controlled reaction mechanism, a kinetic equation quantifying both Sn concentration and alloying element effects was derived and verified by comparing the kinetic data obtained using four different solders with different concentrations of Sn and the alloying elements. Originality/value The similarity between the activation energies of these four solders confirms that the diffusion of Sn atoms through the IMC is the rate-controlling step. Besides, the kinetic values are independent of the geometry of Ni, whether spherical particle or flat substrate.


2014 ◽  
Vol 21 (10) ◽  
pp. 964-968 ◽  
Author(s):  
Lin Cheng ◽  
Kai-ming Wu ◽  
Xiang-liang Wan ◽  
Guo-hong Zhang

2007 ◽  
Vol 539-543 ◽  
pp. 4578-4583 ◽  
Author(s):  
Kai Ming Wu ◽  
A.M. Guo ◽  
Lin Cheng

Three-dimensional observations of proeutectoid ferrite formed at grain boundary in an Fe-0.09%C-1.48%Mn vanadium microalloyed alloy was revealed by techniques of serial sectioning along with computer-aided reconstruction. The ferrite allotriomorphs nucleated at grain boundary edges were approximately prolate ellipsoids. Not all the ferrite allotriomorphs formed at grain boundary faces were oblate ellipsoids. The growth kinetics of ferrite allotriomorphs nucleated at grain boundary edges was greater than that of ferrite allotriomorphs nucleated at grain boundary faces.


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