Investigation on Structural, Dielectric, Thermistor Parameters and Negative Temperature Coefficient Behaviour of Nd, Gd, and La-Doped Bismuth Ferrite

Author(s):  
Priyambada Mallick ◽  
A. K. Sahu ◽  
Susanta Ku. Biswal ◽  
S. K. Satpathy ◽  
Banarji Behera
1998 ◽  
Vol 13 (5) ◽  
pp. 1238-1242 ◽  
Author(s):  
T. Battault ◽  
R. Legros ◽  
A. Rousset

“Aging,” defined as the drift of resistance with temperature after 1000 h, was investigated for iron manganite temperature coefficient thermistors. For these devices, aging is relatively large, about 10%. The cationic distributions before and after aging were determined by Mössbauer spectroscopy. These distributions explain all the x-ray diffraction and correlated electrical data. The origin of the aging observed on iron manganites thermistors has been identified. It is due to the migration of Fe3+ ions from tetrahedral to octahedral sites of the spinel structure in order to reach a structural equilibrium.


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