Optically active transition metal complexes. Part 108. Synthesis, crystal structure and properties of a novel “quasi-meso” dinuclear η6-benzene-ruthenium(II) complex with chiral salicylaldiminato ligands

1996 ◽  
Vol 518 (1-2) ◽  
pp. 47-53 ◽  
Author(s):  
Henri Brunner ◽  
Ralf Oeschey ◽  
Bernd Nuber
Keyword(s):  
Crystal Structure ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Optically Active ◽  
Structure And Properties ◽  
Active Transition

Optisch aktive Übergangsmetall-Komplexe, 122. Synthese von Palladium(II)-Schiff-Base-Komplexen -intramolekulare Wechselwirkungen / Optically Active Transition Metal Complexes, 122. Synthesis of Palladium (II) Complexes with Schiff Base Ligands -Intramolecular Interactions

2000 ◽  
Vol 55 (2) ◽  
pp. 145-154 ◽  
Author(s):  
Henri Brunner ◽  
Markus Niemetz ◽  
Manfred Zabel
Keyword(s):  
Crystal Structure ◽  
Schiff Base ◽  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Optically Active ◽  
Intramolecular Interactions ◽  
Schiff Base Ligands ◽  
Enantiomerically Pure ◽  
Active Transition

Abstract Imines of salicylaldehyde and 2,6-diformyl-p-cresol have been used as ligands in palladium (II) complexes. Enantiomerically pure ligands give enantiomerically pure complexes, racemic ligands give racemates and meso-forms. Differences between the respective isomers of the ligands within the complexes and between the diastereomers of the complexes were investigated. Crystal structure analyses established the trans configuration at the metal center.

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