Dispersion in heterogeneous porous media 1. Local volume averaging and large-scale averaging

Author(s):  
Michel Quintard ◽  
Stephen Whitaker

Most porous media of practical importance are hierarchical in nature; that is, they are characterized by more than one length-scale. When these length-scales are disparate, the hierarchical structure can be analyzed by the method of volume averaging (Anderson and Jackson, 1967; Marie, 1967; Slattery, 1967; Whitaker, 1967). In this approach, macroscopic quantities at a given length-scale are defined in terms of a boundary value problem that describes the phenomena at a smaller length-scale, and information is filtered from one scale to another by a series of volume and area integrals. Other methods, such as ensemble averaging (Matheron, 1965; Dagan, 1989) or homogenization theory (Bensoussan et al, 1978; Sanchez-Palencia, 1980), have been used to study hierarchical systems, and developments specific to the problems under consideration in this chapter can be found in Bourgeat (1984), Auriault (1987), Amaziane and Bourgeat (1988), and Sáez et al. (1989). The transformation from the Darcy scale to the large scale is a recurrent problem in reservoir and aquifer engineering. A detailed description of reservoir properties is available through geostatistical analysis (Journel, 1996) on a fine grid with a length-scale much smaller than the scale of the blocks in the reservoir simulator. “Effective” or “pseudo” properties are assigned to the coarse grid blocks, while the forms of the large-scale equations are required to be the same as those used at the Darcy scale (Coats et al., 1967; Hearn, 1971; Jacks et al., 1972; Kyte and Berry, 1975; Dake, 1978; Killough and Foster, 1979; Yokoyama and Lake, 1981; Kortekaas, 1983; Thomas, 1983; Kossack et al., 1990). A detailed discussion of the comparison between the several approaches is beyond the scope of this chapter; however, one can read Bourgeat et al. (1988) for an introductory comparison between the method of volume averaging and the homogenization theory, and Ahmadi et al. (1993) for a discussion of the various classes of pseudofunction theories.


2021 ◽  
Author(s):  
Marco Dentz ◽  
Alexandre Puyguiraud ◽  
Philippe Gouze

<p>Transport of dissolved substances through porous media is determined by the complexity of the pore space and diffusive mass transfer within and between pores. The interplay of diffusive pore-scale mixing and spatial flow variability are key for the understanding of transport and reaction phenomena in porous media. We study the interplay of pore-scale mixing and network-scale advection through heterogeneous porous media, and its role for the evolution and asymptotic behavior of hydrodynamic dispersion. In a Lagrangian framework, we identify three fundamental mechanisms of pore-scale mixing that determine large scale particle motion: (i) The smoothing of intra-pore velocity contrasts, (ii) the increase of the tortuosity of particle paths, and (iii) the setting of a maximum time for particle transitions. Based on these mechanisms, we derive an upscaled approach that predicts anomalous and normal hydrodynamic dispersion based on the characteristic pore length, Eulerian velocity distribution and Péclet number. The theoretical developments are supported and validated by direct numerical flow and transport simulations in a three-dimensional digitized Berea sandstone sample obtained using X-Ray microtomography. Solute breakthrough curves, are characterized by an intermediate power-law behavior and exponential cut-off, which reflect pore-scale velocity variability and intra-pore solute mixing. Similarly, dispersion evolves from molecular diffusion at early times to asymptotic hydrodynamics dispersion via an intermediate superdiffusive regime. The theory captures the full evolution form anomalous to normal transport behavior at different Péclet numbers as well as the Péclet-dependence of asymptotic dispersion. It sheds light on hydrodynamic dispersion behaviors as a consequence of the interaction between pore-scale mixing and Eulerian flow variability. </p>


Author(s):  
Debenest Gérald ◽  
Michel Quintard

Flows in highly heterogeneous porous media are found in many practical fields, such as hydrology, petroleum engineering, and chemical engineering. The case of two-region heterogeneous media (fractured media, catalytic beds, etc.) plays a fundamental role. The different questions associated with this specific case are illustrated in this paper for two different kinds of transport: (i) flow of a slightly compressible fluid, (ii) dispersion of a tracer. Many different theoretical models are implemented using COMSOL Multiphysics™. These models correspond to direct simulation and macro-scale or large-scale models such as fully averaged models or mixed models.


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