Far-infrared spectra of charge-transfer complexes between IX (X = I, Br, Cl) and some organic sulfides

1972 ◽  
Vol 28 (3) ◽  
pp. 439-446 ◽  
Author(s):  
M. Yamada ◽  
H. Saruyama ◽  
K. Aida
Keyword(s):  
Charge Transfer ◽  
Infrared Spectra ◽  
Far Infrared ◽  
Charge Transfer Complexes ◽  
Organic Sulfides ◽  
Far Infrared Spectra

Far infrared spectra of charge-transfer complexes between iodine and substituted pyridines

1967 ◽  
Vol 297 (1451) ◽  
pp. 440-448 ◽  
Keyword(s):  
Charge Transfer ◽  
Infrared Spectra ◽  
Equilibrium Constants ◽  
Far Infrared ◽  
Charge Transfer Complexes ◽  
Absorption Bands ◽  
Substituted Pyridines ◽  
Stretching Vibration ◽  
Far Infrared Spectra ◽  
Electronic And Steric Effects

Far infrared spectra of charge-transfer complexes between iodine and substituted pyridines, dissolved in cyclohexane, have been measured in the region 20 to 200 cm -1 . Bands have been assigned to the modified iodine molecule stretching vibration near 180 cm -1 , and to the stretching of the intermolecular bond in the range 65 to 95 cm -1 . The shifts of the vibration frequencies, and force constants calculated using a simple valency force field, have been discussed in relation to the mass, electronic and steric effects of substituent groups. Equilibrium constants for the formation of the complex have been determined. From the intensities of the absorption bands, further evidence has been found for a vibronic interaction, leading to a delocalization of the transition moment in the vibrations of the complexes, and to an enhancement of the intensity of absorption.

The far infrared spectra of IBr charge–transfer complexes

1987 ◽  
Vol 86 (12) ◽  
pp. 6665-6668 ◽  
Author(s):  
Roseanne J. Sension ◽  
Herbert L. Strauss
Keyword(s):  
Charge Transfer ◽  
Infrared Spectra ◽  
Far Infrared ◽  
Charge Transfer Complexes ◽  
Far Infrared Spectra

Far-infrared spectra of polycrystallineBa2YCu3O9−δ

1987 ◽  
Vol 36 (1) ◽  
pp. 846-849 ◽  
Author(s):  
G. A. Thomas ◽  
H. K. Ng ◽  
A. J. Millis ◽  
R. N. Bhatt ◽  
R. J. Cava ◽  
...  
Keyword(s):  
Infrared Spectra ◽  
Far Infrared ◽  
Far Infrared Spectra
Sign in / Sign up

Export Citation Format

Share Document