scholarly journals Vanadium oxide supported on porous clay heterostructure for the partial oxidation of hydrogen sulphide to sulfur

2015 ◽  
Vol 254 ◽  
pp. 36-42 ◽  
Author(s):  
M.D. Soriano ◽  
J.A. Cecilia ◽  
A. Natoli ◽  
J. Jiménez-Jiménez ◽  
J.M. López Nieto ◽  
...  
1931 ◽  
Vol 0 (0) ◽  
pp. 1809-1827 ◽  
Author(s):  
Harold Warris Thompson ◽  
Norman Stanley Kelland

2018 ◽  
Vol 54 (2) ◽  
pp. 136-146 ◽  
Author(s):  
V. A. Savelieva ◽  
A. M. Starik ◽  
N. S. Titova ◽  
O. N. Favorskii

1979 ◽  
Vol 12 (4) ◽  
pp. 451-456 ◽  
Author(s):  
E. Alabiso ◽  
P. Ciambelli ◽  
V. De Simone ◽  
C. Porcellu ◽  
R. Valentino

Author(s):  
Satohiro Yoshida ◽  
Yasuhiro Magatani ◽  
Shigeyoshi Noda ◽  
Takuzo Funabiki

Author(s):  
Van D. N Nguyen ◽  
Dongmin Yun ◽  
Nataphan Sakulchaicharoen ◽  
José E Herrera

Abstract A series of vanadium oxide (VOx) catalysts prepared using three different supports were tested for the partial oxidation of ethanol to acetaldehyde. Optical absorption spectroscopy and Temperature Programmed reductions experiments indicate that the reducibility and average domain size of the vanadia clusters anchored on the supports are very sensitive to vanadia loading. The catalytic activity results were modeled using a pseudo steady state approximation using the ethanol hydrogen abstraction step as rate limiting. The results obtained strongly suggest that catalytic activity can be correlated to both average vanadia cluster size and the ability of vanadia to uptake hydrogen during TPR experiments.


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