The sensitivity of simulated aerosol climatic impact to domain size using regional model (WRF-Chem v3.6)

Domain size can have significant impact on regional modeling results, but few studies examined the sensitivities of simulated aerosol impact to regional domain size. This study investigates the regional modeling sensitivities of aerosol impact on the East Asian summer monsoon (EASM) to domain size. The simulations with two different domain sizes demonstrate consistently that aerosols induce the cooling of the lower troposphere that leads to the anticyclone circulation anomalies and thus the weakening of EASM moisture transport. The aerosol-induced adjustment of monsoonal circulation results in an alternate increase and decrease pattern of precipitation over China. Domain size has a great influence on the simulated meteorological fields. For example, the simulation with larger domain size produces weaker EASM circulation, which also affects aerosol distributions significantly. This leads to the difference of simulated strength and area extent of aerosol-induced changes of lower-tropospheric temperature and pressure, which further results in different distributions of circulation and precipitation anomalies over China. For example, over southeastern China, aerosols induce the increase (decrease) of precipitation from the smaller-domain (larger-domain) simulation. Different domain sizes consistently simulate an aerosol-induced increase in precipitation around 30∘ N over eastern China. This study highlights the important influence of domain size on regional modeling results of aerosol impact on circulation and precipitation, which may not be limited to East Asia. More generally, this study also implies that proper modeling of meteorological fields with appropriate domain size is one of the keys to simulating robust aerosol climatic impact.

Evaluation of Mei-yu heavy-rainfall quantitative precipitation forecasts in Taiwan by a cloud-resolving model for three seasons of 2012–2014

In this study, the performance of quantitative precipitation forecasts (QPFs) by the Cloud-Resolving Storm Simulator (CReSS) in Taiwan, at a horizontal grid spacing of 2.5 km and a domain size of 1500×1200 km2, in the range of 1–3 d during three Mei-yu seasons (May–June) of 2012–2014 is evaluated using categorical statistics, with an emphasis on heavy-rainfall events (≥100 mm per 24 h). The categorical statistics are chosen because the main hazards are landslides and floods in Taiwan, so predicting heavy rainfall at the correct location is important. The overall threat scores (TSs) of QPFs for all events on day 1 (0–24 h) are 0.18, 0.15, and 0.09 at thresholds of 100, 250, and 500 mm, respectively, and indicate considerable improvements at increased resolution compared to past results and 5 km models (TS < 0.1 at 100 mm and TS ≤ 0.02 at 250 mm). Moreover, the TSs are shown to be higher and the model more skillful in predicting larger events, in agreement with earlier findings for typhoons. After classification based on observed rainfall, the TSs of day − 1 QPFs for the largest 4 % of events by CReSS at 100, 250, and 500 mm (per 24 h) are 0.34, 0.24, and 0.16, respectively, and can reach 0.15 at 250 mm on day 2 (24–48 h) and 130 mm on day 3 (48–72 h). The larger events also exhibit higher probability of detection and lower false alarm ratio than smaller ones almost without exception across all thresholds. With the convection and terrain better resolved, the strength of the model is found to lie mainly in the topographic rainfall in Taiwan rather than migratory events that are more difficult to predict. Our results highlight the crucial importance of cloud-resolving capability and the size of fine mesh for heavy-rainfall QPFs in Taiwan.

On modelling of thermodynamic interaction of particles suspended in two-dimensional medium

Analytical description of temperature distribution in a medium with foreign inclusions is difficult due to the complicated geometry of the problem, so asymptotic and numerical methods are usually used to model thermodynamic processes in heterogeneous media. To be convinced in convergence of these methods the authors consider model problem about two identical round particles in infinite planar medium with temperature gradient which is constant at infinity. Authors refine multipole expansion of the solution obtained earlier by continuing it up to higher powers of small parameter, that is nondimensional radius of thermodynamically interacting particles. Numerical approach to the problem using ANSYS software is described; in particular, appropriate choice of approximate boundary conditions is discussed. Authors ascertain that replacement of infinite medium by finite-sized domain is important source of error in FEM. To find domain boundaries in multiple inclusions’ problem the authors develop “fictituous particle” method; according to it the cloud of particles far from the center of the cloud acts approximately as a single equivalent particle of greater size and so may be replaced by it. Basing on particular quantitative data the dependence of domain size that provides acceptable accuracy on thermal conductivities of medium and of particles is explored. Authors establish series of numerical experiments confirming convergence of multipole expansions method and FEM as well; proximity of their results is illustrated, too.

Controlling foamability of polypropylene/γ-irradiated ethylene acrylic elastomer blends by extent of crosslinking and domain microstructure of elastomer

Foams of polypropylene/elastomer blends can often lead to softer foams which may not be desirable every time. Incorporating rigidity to the foams can often be made possible by preferentially crosslinking the elastomer phase prior to blending. Although foamability of polypropylene/elastomer blends has been understood in the scientific community, the influence of the extent of crosslinking in the elastomer phase is not yet understood well. The purpose of this investigation is to identify the influence of the extent of elastomer crosslinking and the blend morphological attributes (achieved by varying screw speed during melt mixing) on foamability of polypropylene/partially crosslinked elastomer blends. Crosslinking of ethylene-acrylic elastomer is carried out using gamma radiation with several doses (0, 12.5, 25, 50 kGy) before melt blending and, subsequently, 10 wt.% of the irradiated elastomers (prior optimized) are mixed with polypropylene in a micro-compounder at three different screw speeds. The microstructure development in blends is characterized by scanning electron microscopy. Frequency sweep rheological analysis is done for selected blends to identify the ease of foamability among the series of blends. Foaming of blends is done with supercritical carbon dioxide in batch mode at three different temperatures. The density reduction along with the microcellular morphology development of blends with foaming is analyzed with the screw speed, the extent of crosslinking, and foaming temperature; furthermore, the individual input parameters (the elastomer domain size, controlled by the screw speed and the extent of crosslinking, controlled by gamma radiation dose) are optimized based on the foam morphology. A uniform and good foamability were achieved at 155 and 160°C for blends with elastomers, irradiated at 12.5 and 25 kGy radiation doses. The lowest density foam (0.37 g/cc) was obtained for polypropylene with 12.5 kGy irradiated crosslinked elastomer mixed at 200 rpm at 160°C foaming temperature. The final elastomer domain dispositions within the foam morphologies are characterized and the plausible foaming mechanism is proposed.

Growth kinetics and power laws indicate distinct mechanisms of cell-cell interactions in the aggregation process

Cellular aggregation is a complex process orchestrated by various kinds of interactions depending on its environments. Different interactions give rise to different pathways of cellular rearrangement and the development of specialized tissues. To distinguish the underlying mechanisms, in this theoretical work, we investigate the spontaneous emergence of tissue patterns from an ensemble of single cells on a substrate following three leading pathways of cell-cell interactions, namely, direct cell adhesion contacts, matrix mediated mechanical interaction, and chemical signalling. Our analysis shows that the growth kinetics of the aggregation process is distinctly different for each pathway and bears the signature of the specific cell-cell interactions. Interestingly, we find that the average domain size and the mass of the clusters exhibit a power law growth in time under certain interaction mechanisms hitherto unexplored. Further, as observed in experiments, the cluster size distribution can be characterized by stretched exponential functions showing distinct cellular organization processes.

Graded Morphologies and the Performance of PffBT4T-2OD:PC71BM Devices Using Additive Choice

The impact of several solvent processing additives (1-chloronaphthalene, methylnaphthalene, hexadecane, 1-phenyloctane, and p-anisaldehyde), 3% v/v in o-dichlorobenzene, on the performance and morphology of poly[(5,6-difluoro-2,1,3-benzothiadiazol-4,7-diyl)-alt-(3,3‴-di(2-octyldodecyl)-2,2′,5′,22033,5″,2‴-quaterthiophen-5,5‴-diyl)] (PffBT4T-2OD):[6,6]-phenyl-C71-butyric acid methyl ester (PC71BM)-based polymer solar cells was investigated. Some additives were shown to enhance the power conversion efficiency (PCE) by ~6%, while others decreased the PCE by ~17–25% and a subset of the additives tested completely eliminated any power conversion efficiency and the operation as a photovoltaic device. Grazing-Incidence Wide Angle X-ray Scattering (GIWAXS) revealed a clear stepwise variation in the crystallinity of the systems when changing the additive between the two extreme situations of maximum PCE (1-chloronaphthalene) and null PCE (hexadecane). Small-Angle Neutron Scattering (SANS) revealed that the morphology of devices with PCE ~0% was composed of large domains with correlation lengths of ~30 nm, i.e., much larger than the typical exciton diffusion length (~12 nm) in organic semiconductors. The graded variations in crystallinity and in nano-domain size observed between the two extreme situations (1-chloronaphthalene and hexadecane) were responsible for the observed graded variations in device performance.

Thermal transport in beta-gallium oxide thin-film using non-gray Boltzmann transport equation

Phonon transport in β-Ga2O3 thin films and metal–oxide field effect transistors (MESFETs) are investigated using non-gray Boltzmann transport equations (BTE) to decipher the effect of ballistic-diffusive phonon transport. The effects of domain size, and energy dissipation to various phonon modes and subsequent phonon-phonon energy exchange on the thermal transport and temperature distribution is investigated using non-gray BTE. Our analysis deciphered that domain size plays a major role in thermal transport in β-Ga2O3 but energy dissipation to various phonon modes and subsequent phonon-phonon energy exchange does not affect the temperature field significantly. Phonon transport in β-Ga2O3 MESFETs on diamond substrate is investigated using coupled non-gray BTE and Fourier model. It is established that the ballistic effects need to be considered for devices with β-Ga2O3 layer thickness less than 1 µm. A non-gray phonon BTE model should be used near hotspot in the thin β-Ga2O3 layer as the Fourier model may not give accurate temperature distribution. The results from this work will help in understanding the mechanism of phonon transport in the β-Ga2O3 thin films and energy efficient design of its FETs.

Efficient realization of infrared coherent radiation by the method of parametric light amplification in nonlinear photonic crystals

The process of parametric amplification of light from short laser pulses in nonlinear photonic crystals is analyzed numerically. The calculations were carried out taking into account the effects of the dispersion of the medium up to the third order and cubic nonlinearity of the Kerr type. It is shown that a change in the size of domains can significantly affect the formation of a signal wave pulse. On the basis of the results obtained, we analyzed the optimal values of the domain size at which the efficient energetic generation of the signal wave is observed.