How the Horváth paradigm, Fluorous Biphasic Catalysis, affected oxidation chemistry: Successes, challenges, and a sustainable future

2019 ◽  
Vol 380 ◽  
pp. 584-599 ◽  
Author(s):  
Jean-Marc Vincent ◽  
Maria Contel ◽  
Gianluca Pozzi ◽  
Richard H. Fish
Keyword(s):  
Biphasic Catalysis ◽  
Sustainable Future ◽  
Oxidation Chemistry ◽  
Fluorous Biphasic Catalysis

New bis(fluoro-ponytailed) bipyridine ligands for Pd-catalyzed Heck reactions under fluorous biphasic catalysis condition

Tetrahedron ◽  
2007 ◽  
Vol 63 (9) ◽  
pp. 2019-2023 ◽  
Author(s):  
Norman Lu ◽  
Yan-Chou Lin ◽  
Jeng-Yung Chen ◽  
Chi-Wen Fan ◽  
Ling-Kang Liu
Keyword(s):  
Heck Reactions ◽  
Biphasic Catalysis ◽  
Catalysis Condition ◽  
Fluorous Biphasic Catalysis

Ytterbium perfluorooctanesulfonate catalyzed synthesis of acylals from aldehydes and acetic anhydride in a fluorous biphasic system

2006 ◽  
Vol 84 (11) ◽  
pp. 1563-1566 ◽  
Author(s):  
Wen-Bin Yi ◽  
Ya-Qing Yin ◽  
Chun Cai
Keyword(s):  
Acetic Anhydride ◽  
Significant Loss ◽  
Biphasic System ◽  
Efficient Synthesis ◽  
Biphasic Catalysis ◽  
Highly Efficient ◽  
Fluorous Biphasic Catalysis

Ytterbium perfluorooctanesulfonate [Yb(OPf)3] catalyses the highly efficient synthesis of acylals from aldehydes and acetic anhydride in a fluorous biphase system (FBS) composed of toluene and perfluorodecalin. The fluorous phase containing the fluorous catalyst is easily separated and can be reused several times without significant loss of catalytic activity.Key words: acylals, ytterbium perfluorooctanesulfonate, fluorous biphasic catalysis.

Fluorous Biphasic Catalysis Without Perfluorinated Solvents: Application to Pd-Mediated Suzuki and Sonogashira Couplings.

ChemInform ◽  
2003 ◽  
Vol 34 (14) ◽  
Author(s):  
Carl Christoph Tzschucke ◽  
Christian Markert ◽  
Heiko Glatz ◽  
Willi Bannwarth
Keyword(s):  
Biphasic Catalysis ◽  
Fluorous Biphasic Catalysis
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