Computational advances aiding mechanistic understanding of silver-catalyzed carbene/nitrene/silylene transfer reactions

2019 ◽  
Vol 382 ◽  
pp. 69-84 ◽  
Author(s):  
Jing Zhang ◽  
Chunhui Shan ◽  
Tao Zhang ◽  
Jinshuai Song ◽  
Tao Liu ◽  
...  
Keyword(s):  
Transfer Reactions ◽  
Mechanistic Understanding ◽  
Silylene Transfer

Silylene-transfer reactions of cyclic organosilanes induced by phenanthraquinone triplet

2001 ◽  
Vol 636 (1-2) ◽  
pp. 63-68 ◽  
Author(s):  
Masahiro Kako ◽  
Masumi Ninomiya ◽  
Mei Gu ◽  
Yasuhiro Nakadaira ◽  
Masanobu Wakasa ◽  
...  
Keyword(s):  
Transfer Reactions ◽  
Silylene Transfer

Silver‐Catalyzed Carbene, Nitrene, and Silylene Transfer Reactions

2018 ◽  
pp. 439-532 ◽  
Author(s):  
Mahzad Dehghany ◽  
Josephine Eshon ◽  
Jessica M. Roberts ◽  
Jennifer M. Schomaker
Keyword(s):  
Transfer Reactions ◽  
Silylene Transfer

Thermolysis of 1,1 -dimesityl-3-phenyl-2-trimethylsilyl-1-silacyclopropene: silylene transfer reactions to 1,4-bis(silyl)butadiynes

1997 ◽  
Vol 545-546 ◽  
pp. 611-613 ◽  
Author(s):  
Atsutaka Kunai ◽  
Toshiyuki Mihara ◽  
Yoichi Matsuo ◽  
Joji Ohshita ◽  
Akinobu Naka ◽  
...  
Keyword(s):  
Transfer Reactions ◽  
Silylene Transfer

scholarly journals Diastereoselective silylene transfer reactions to chiral enantiopure alkenes: effects of ligand size and substrate bias

2017 ◽  
Vol 46 (27) ◽  
pp. 8763-8768 ◽  
Author(s):  
Christina Z. Rotsides ◽  
K. A. Woerpel
Keyword(s):  
Transfer Reactions ◽  
Metal Catalyst ◽  
Substrate Bias ◽  
Silylene Transfer ◽  
Steric Hinderance

When silylene transfer reactions are irreversible, the steric hinderance of the alkene and ligands on the metal catalyst does not influence stereoselectivity, but when the reaction is reversible (above), silyene transfer reactions can be diastereoselective.

Photo-induced silylene-transfer reactions of cyclic organosilanes to phenanthraquinone

1997 ◽  
pp. 1373-1374 ◽  
Author(s):  
Masahiro Kako ◽  
Masumi Ninomiya ◽  
Yasuhiro Nakadaira
Keyword(s):  
Transfer Reactions ◽  
Silylene Transfer
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