silylene transfer
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Computational advances aiding mechanistic understanding of silver-catalyzed carbene/nitrene/silylene transfer reactions

2019 ◽  
Vol 382 ◽  
pp. 69-84 ◽  
Author(s):  
Jing Zhang ◽  
Chunhui Shan ◽  
Tao Zhang ◽  
Jinshuai Song ◽  
Tao Liu ◽  
...  
Keyword(s):  
Transfer Reactions ◽  
Mechanistic Understanding ◽  
Silylene Transfer

Silver‐Catalyzed Carbene, Nitrene, and Silylene Transfer Reactions

2018 ◽  
pp. 439-532 ◽  
Author(s):  
Mahzad Dehghany ◽  
Josephine Eshon ◽  
Jessica M. Roberts ◽  
Jennifer M. Schomaker
Keyword(s):  
Transfer Reactions ◽  
Silylene Transfer

scholarly journals Diastereoselective silylene transfer reactions to chiral enantiopure alkenes: effects of ligand size and substrate bias

2017 ◽  
Vol 46 (27) ◽  
pp. 8763-8768 ◽  
Author(s):  
Christina Z. Rotsides ◽  
K. A. Woerpel
Keyword(s):  
Transfer Reactions ◽  
Metal Catalyst ◽  
Substrate Bias ◽  
Silylene Transfer ◽  
Steric Hinderance

When silylene transfer reactions are irreversible, the steric hinderance of the alkene and ligands on the metal catalyst does not influence stereoselectivity, but when the reaction is reversible (above), silyene transfer reactions can be diastereoselective.

ChemInform Abstract: Diastereoselective Synthesis of Seven-Membered-Ring trans-Alkenes from Dienes and Aldehydes by Silylene Transfer.

ChemInform ◽  
2013 ◽  
Vol 44 (6) ◽  
pp. no-no
Author(s):  
Margaret A. Greene ◽  
Michel Prevost ◽  
Joshua Tolopilo ◽  
K. A. Woerpel
Keyword(s):  
Membered Ring ◽  
Diastereoselective Synthesis ◽  
Silylene Transfer

scholarly journals Diastereoselective Synthesis of Seven-Membered-Ring trans-Alkenes from Dienes and Aldehydes by Silylene Transfer

2012 ◽  
Vol 134 (30) ◽  
pp. 12482-12484 ◽  
Author(s):  
Margaret A. Greene ◽  
Michel Prévost ◽  
Joshua Tolopilo ◽  
K. A. Woerpel
Keyword(s):  
Membered Ring ◽  
Diastereoselective Synthesis ◽  
Silylene Transfer

ChemInform Abstract: Silver-Catalyzed Silylene Transfer

ChemInform ◽  
2011 ◽  
Vol 42 (30) ◽  
pp. no-no
Author(s):  
Tom G. Driver
Keyword(s):  
Silylene Transfer

scholarly journals Silylene Transfer to Allylic Sulfides: Formation of Substituted Silacyclobutanes

2010 ◽  
Vol 75 (16) ◽  
pp. 5729-5732 ◽  
Author(s):  
Bryan J. Ager ◽  
Laura E. Bourque ◽  
Kay M. Buchner ◽  
K. A. Woerpel
Keyword(s):  
Silylene Transfer
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