scholarly journals Organic facies variability and paleoenvironmental changes on the Moroccan Atlantic coast across the Cenomanian—Turonian Oceanic Anoxic Event (OAE2)

2020 ◽  
Vol 230 ◽  
pp. 103587
Author(s):  
Carolina Fonseca ◽  
João Graciano Mendonça Filho ◽  
Carine Lézin ◽  
Luís V. Duarte
2019 ◽  
Author(s):  
Carolina Fonseca ◽  
João Graciano Mendonça Filho ◽  
Carine Lézin ◽  
Luís Vítor Duarte ◽  
Philippe Fauré

The Early Toarcian is characterized by major worldwide environmental changes recorded in an organic-rich black shale sedimentation and carbon cycle disturbances, the so-called Toarcian Oceanic Anoxic Event (T-OAE) (e.g. Jenkyns, 2010). This organic-rich sedimentation is particularly recorded in shallow marine epicontinental basins that developed as part of the Toarcian European epicontinental shelf, paleogeographical framework in which the Pyrenean Basin is incorporated (e.g. Fonseca et al., 2018; McArthur et al., 2008). With these premises, the main objective of this study is to assess the organic facies variability and to define the depositional paleoenvironments of two sections from the Pyrenean Basin (Bizanet and Pont de Suert) during the T-OAE, using palynofacies and geochemical (Total Organic Carbon - TOC and insoluble residue - IR) data. The Pyrenean tectonics that occurred between the latest Cretaceous and the Oligocene, deformed, detached and fragmented the substrate resulting in diverse tectonic units (Faure, 2002). The late Pliensbachian-early Toarcian of the Pont de Suert section, located in the South Pyrenean zone, is characterized by the limestone dominated Barre a Pecten Formation (Fm.), and the carbonate and/or argillaceous-carbonate alternation of its three members (alternations of marl and argillaceous limestone of the Calcaires argileux à Spirifèrines Member (Mb.), the argillaceous limestones and marls of the Calcaires argileux et marnes à Soaresirhynchia Mb., and the marl and argillaceous limestone dominated Calcaires argileux à Telothyris Mb.; Faure, 2002). The Bizanet section is located in the eastern Corbières, and is characterized by a 3m thick succession of late Pliensbachian-early Toarcian sediments comprising, at the base, the limestone dominated Barre a Pecten Fm., followed by a sedimentary gap dated to the Tenuicostatum Chronozone, topped by the marly dominated succession of the Bizanet Fm. (black ferruginous marls intercalated with limestones and topped by dolomitic limestones of the Schistes carton Mb., and the black marls of the Argilites noires litées Mb.; Faure, 2002). The geochemical results evidenced that the Bizanet section presents higher TOC contents than the Pont de Suert section, with values reaching 2.03 wt.%. In the Bizanet section IR ranges between 12 wt.% and 82 wt.% and in the Pont de Suert section varies from 13wt.% to 67 wt.%, displaying a similar average value for the two sections (45 wt.%). The palynofacies assemblage is dominated in both sections by the same components, belonging to the Phylum Cnidaria, Class Hydrozoa and Order Hydroida, and are represented by fragments of colonial and non-colonial sessile polypoid forms and free-swimming medusoid forms, with different degrees of amorphization. (This abstract has been truncated, please see the complete PDF version)


2021 ◽  
Author(s):  
Carolina Fonseca ◽  
João Graciano Mendonça Filho ◽  
Matías Reolid ◽  
Luís Vítor Duarte ◽  
Carine Lézin

<p>The Cenomanian—Turonian boundary is marked by one of the warmest periods of the Mesozoic, associated with high <em>p</em>CO<sub>2</sub> levels and global sea-level highstands. Coupled to these extreme conditions is a massive magmatic episode, the establishment of worldwide marine anoxia, the deposition of organic-rich facies, and perturbations of the global carbon cycle, the so-called Oceanic Anoxic Event 2 (OAE2). In order to define the organic facies variability, this stratigraphic interval was analysed in the Baños de la Hedionda, a reference section positioned in the W part of the Internal Subbetic, representing the sedimentary record of a pelagic plateau located in the most distal part of the South Iberian Paleomargin. Regarding this goal, a high resolution study was developed on the Capas Blancas Formation (Capas Blancas, Black radiolaritic shales, and Boquerón members – Mb.), using organic petrographic and geochemical techniques. Carbon isotopic profile, for the isolated kerogen (δ<sup>13</sup>C<sub>kerogen</sub>), displays a positive excursion of ~2.5‰ observed in the Black radiolaritic shales Mb., which is in accordance with the worldwide recognized trend for the OAE2 isotopic record.</p><p>The pre-OAE2 is represented by the Capas Blancas Mb., with the majority of the samples of this unit showing no organic matter (OM) recovery (0.01—0.57 wt.% total organic carbon; TOC). Palynofacies analysis displayed an association co-dominated by the Amorphous and Palynomorph groups. The Amorphous Group is characterized mostly by marine phytoplankton-derived amorphous OM (AOM), while the Palynomorph Group is co-dominated by freshwater microplankton (Zygnemataceae and <em>Closteriu</em><span><em>m</em>) and choanoflagellates, with some specimens of marine microplankton, sporomorphs, and zoomorphs being also identified. The mixture of freshwater and marine components suggest deposition in a platform environment with shallow depths and oscillating oxygen regimen (oxic to dysoxic conditions). The freshwater components are most likely transported into the marine system due to the lower amorphization state, with the source area being in high proximity.</span></p><p>The OAE2, represented by the Black radiolaritic shales Mb., is characterized by a dominance of: (i) marine phytoplankton-derived AOM; (ii) plate-like bacterial AOM; and, (iii) sheet-like bacterial AOM with a cratered aspect (0.36—31.48 wt.% TOC). Choanoflagelates (with high degree of amorphization) at the base of the unit, zooclasts, sporomorphs, and solid bitumen are also present. The change in the organic facies suggests the occurrence of a transgressive phase. This organic facies is indicative of a relative sea level rise, with O<sub>2</sub> conditions deteriorating with the emplacement of reducing conditions, possibly related to an increase in primary productivity.</p><p>The post-OAE2, recognized in the Boquerón Mb., is characterized by a co-dominance of marine phytoplankton-derived AOM and palynomorphs, namely zoomorphs, and high percentages of opaque phytoclasts (below 0.25 wt.% TOC). Nevertheless, kerogen displays a reworked character and, therefore, data should be used with caution.</p><p>Furthermore, this study constitutes the first record of <em>Closterium</em> in sediments from the Cretaceous, and the first identification of choanoflagellates, the closest living relatives of Metazoa, in the fossil record.</p>


2018 ◽  
Vol 190 ◽  
pp. 218-235 ◽  
Author(s):  
Carolina Fonseca ◽  
João Graciano Mendonça Filho ◽  
Carine Lézin ◽  
Luis V. Duarte ◽  
Phillipe Fauré

2019 ◽  
Author(s):  
Carolina Fonseca ◽  
João Graciano Mendonça Filho ◽  
Carine Lézin ◽  
Luís Vítor Duarte ◽  
Philippe Fauré

The Early Toarcian is characterized by major worldwide environmental changes recorded in an organic-rich black shale sedimentation and carbon cycle disturbances, the so-called Toarcian Oceanic Anoxic Event (T-OAE) (e.g. Jenkyns, 2010). This organic-rich sedimentation is particularly recorded in shallow marine epicontinental basins that developed as part of the Toarcian European epicontinental shelf, paleogeographical framework in which the Pyrenean Basin is incorporated (e.g. Fonseca et al., 2018; McArthur et al., 2008). With these premises, the main objective of this study is to assess the organic facies variability and to define the depositional paleoenvironments of two sections from the Pyrenean Basin (Bizanet and Pont de Suert) during the T-OAE, using palynofacies and geochemical (Total Organic Carbon - TOC and insoluble residue - IR) data. The Pyrenean tectonics that occurred between the latest Cretaceous and the Oligocene, deformed, detached and fragmented the substrate resulting in diverse tectonic units (Faure, 2002). The late Pliensbachian-early Toarcian of the Pont de Suert section, located in the South Pyrenean zone, is characterized by the limestone dominated Barre a Pecten Formation (Fm.), and the carbonate and/or argillaceous-carbonate alternation of its three members (alternations of marl and argillaceous limestone of the Calcaires argileux à Spirifèrines Member (Mb.), the argillaceous limestones and marls of the Calcaires argileux et marnes à Soaresirhynchia Mb., and the marl and argillaceous limestone dominated Calcaires argileux à Telothyris Mb.; Faure, 2002). The Bizanet section is located in the eastern Corbières, and is characterized by a 3m thick succession of late Pliensbachian-early Toarcian sediments comprising, at the base, the limestone dominated Barre a Pecten Fm., followed by a sedimentary gap dated to the Tenuicostatum Chronozone, topped by the marly dominated succession of the Bizanet Fm. (black ferruginous marls intercalated with limestones and topped by dolomitic limestones of the Schistes carton Mb., and the black marls of the Argilites noires litées Mb.; Faure, 2002). The geochemical results evidenced that the Bizanet section presents higher TOC contents than the Pont de Suert section, with values reaching 2.03 wt.%. In the Bizanet section IR ranges between 12 wt.% and 82 wt.% and in the Pont de Suert section varies from 13wt.% to 67 wt.%, displaying a similar average value for the two sections (45 wt.%). The palynofacies assemblage is dominated in both sections by the same components, belonging to the Phylum Cnidaria, Class Hydrozoa and Order Hydroida, and are represented by fragments of colonial and non-colonial sessile polypoid forms and free-swimming medusoid forms, with different degrees of amorphization. (This abstract has been truncated, please see the complete PDF version)


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