Mechanistic model of the oxygen reduction catalyzed by a metal-free porphyrin in one- and two-phase liquid systems

2013 ◽  
Vol 110 ◽  
pp. 816-821 ◽  
Author(s):  
Antonín Trojánek ◽  
Jan Langmaier ◽  
Stanislav Záliš ◽  
Zdeněk Samec
1992 ◽  
Vol 57 (7) ◽  
pp. 1419-1423
Author(s):  
Jindřich Weiss

New data on critical holdups of dispersed phase were measured at which the phase inversion took place. The systems studied differed in the ratio of phase viscosities and interfacial tension. A weak dependence was found of critical holdups on the impeller revolutions and on the material contactor; on the contrary, a considerable effect of viscosity was found out as far as the viscosity of continuous phase exceeded that of dispersed phase.


AIChE Journal ◽  
1966 ◽  
Vol 12 (4) ◽  
pp. 795-801 ◽  
Author(s):  
Irwin Pliskin ◽  
Robert E. Treybal

2019 ◽  
Author(s):  
Zurwa Khan ◽  
Reza Tafreshi ◽  
Matthew Franchek ◽  
Karolos Grigoriadis

Abstract Pressure drop estimation across orifices for two-phase liquid-gas flow is essential to size valves and pipelines and decrease the probability of unsafe consequences or high costs in petroleum, chemical, and nuclear industries. While numerically modeling flow across orifices is a complex task, it can assess the effect of numerous orifice designs and operation parameters. In this paper, two-phase flow across orifices has been numerically modeled to investigate the effect of different fluid combinations and orifice geometries on pressure drop. The orifice is assumed to be located in a pipe with fully-developed upstream and downstream flow. Two liquid-gas fluid combinations, namely water-air, and gasoil liquid-gas mixture were investigated for different orifice to pipe area ratios ranging from 0.01 to 1 for the superficial velocity of 10 m/s. Volume of Fluid multiphase flow model along with k-epsilon turbulence model were used to estimate the pressure distribution of liquid-gas mixture along the pipe. The numerical model was validated for water-air with mean relative error less than 10.5%. As expected, a decrease in orifice to pipe area ratio resulted in larger pressure drops due to an increase in the contraction coefficients of the orifice assembly. It was also found that water-air had larger pressure drops relative to gasoil mixture due to larger vortex formation downstream of orifices. In parallel, a mechanistic model to directly estimate the local two-phase pressure drop across orifices was developed. The gas void fraction was predicted using a correlation by Woldesemayat and Ghajar, and applied to separated two-phase flow undergoing contraction and expansion due to an orifice. The model results were validated for different orifices and velocities, with the overall relative error of less than 40%, which is acceptable due to the uncertainties associated with measuring experimental pressure drop. Comparison of the developed numerical and mechanistic model showed that the numerical model is able to achieve a higher accuracy, while the mechanistic model requires minimal computation.


1971 ◽  
Vol 49 (6) ◽  
pp. 872-875 ◽  
Author(s):  
D. D. Esch ◽  
P. J. D'ANGELO ◽  
R. W. Pike

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