Three-dimensional lanthanide metal–organic frameworks with the fluorene-based carboxylate ligands: Syntheses, structures, and properties

2014 ◽  
Vol 413 ◽  
pp. 38-44 ◽  
Author(s):  
Xin-Hui Zhou ◽  
Liang Li ◽  
Ao Li ◽  
Tao Yang ◽  
Wei Huang
Keyword(s):  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Carboxylate Ligands ◽  
Structures And Properties ◽  
Metal Organic ◽  
Lanthanide Metal

Synthesis, Structures, and Properties of Two Three-Dimensional Metal–Organic Frameworks, Based on Concurrent Ligand Extension

2012 ◽  
Vol 51 (12) ◽  
pp. 6498-6506 ◽  
Author(s):  
Dabin Shi ◽  
Yanwei Ren ◽  
Huanfeng Jiang ◽  
Bowei Cai ◽  
Jiaxian Lu
Keyword(s):  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Structures And Properties ◽  
Metal Organic

Syntheses, structures and properties of novel 3D lanthanide metal-organic frameworks with paddle-wheel building blocks

2008 ◽  
Vol 361 (7) ◽  
pp. 2115-2122 ◽  
Author(s):  
Li-Qiong Yu ◽  
Ru-Dan Huang ◽  
Yan-Qing Xu ◽  
Tian-Fu Liu ◽  
Wei Chu ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Building Blocks ◽  
Paddle Wheel ◽  
Structures And Properties ◽  
Metal Organic ◽  
Lanthanide Metal

scholarly journals Simple, Scalable Mechanosynthesis of Metal-Organic Frameworks Using Liquid-Assisted Resonant Acoustic Mixing (LA-RAM)

2020 ◽  
Author(s):  
Hatem M. Titi ◽  
Jean-Louis Do ◽  
Ashlee J. Howarth ◽  
Karthik Nagapudi ◽  
Tomislav Friscic
Keyword(s):  
Metal Organic Frameworks ◽  
Scale Up ◽  
Three Dimensional ◽  
Mixed Ligand ◽  
Carboxylate Ligands ◽  
Metal Organic ◽  
Resonant Acoustic Mixing

We present a methodology for the rapid and readily scalable mechanosynthesis of diverse metal-organic frameworks (MOFs) in the absence of milling media, typically required for other types of mechanochemical syntheses. We demonstrate the use of liquid-assisted resonant acoustic mixing (LA-RAM) methodology for the synthesis of two- and three-dimensional MOFs based on Zn, Co(II) and Cu(II), including single- and mixed-ligand systems, imidazolate or carboxylate ligands. The LA-RAM approach also allowed the synthesis of the ZIF-L, a framework never previously obtained in a solventless environment, as well as its Co(II) analogue. Straightforward scale-up from milligrams to at least 25 grams is demonstrated using ZIF-L as the model.<br>

Complex three-dimensional lanthanide metal–organic frameworks with variable coordination spheres based on pyrazine-2,3,5,6-tetracarboxylate

CrystEngComm ◽  
2015 ◽  
Vol 17 (29) ◽  
pp. 5377-5388 ◽  
Author(s):  
Conrad W. Ingram ◽  
Geoffrey Kibakaya ◽  
John Bacsa ◽  
Stephan R. Mathis,II ◽  
Alvin A. Holder ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Coordination Spheres ◽  
Variable Coordination

An open 3-D MOF with complex connectivity of multi-topic pyrazine-2,3,5,6-tetracarboxylate linker and Ln(iii) ions.

Structural Diversity of Four Lanthanide Metal-Organic Frameworks based on 2,6-Naphthalenedicarboxylate: Synthesis, Structures and Photoluminescent Properties

CrystEngComm ◽  
2021 ◽  
Author(s):  
Ana Chatenever ◽  
Joe E Matsuoka ◽  
Stanley J Wang ◽  
Beatriz Ehlke ◽  
Pierre LeMagueres ◽  
...  
Keyword(s):  
Crystal Structures ◽  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Structural Diversity ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Organic Linker

We report the crystal structures of four different neutral lanthanide (Ln = La, Nd, Eu and Gd) metal-organic frameworks based on the organic linker 2,6-naphthalenedicarboxylate (NDC). The materials are three-dimensional...

Efficient luminescence sensing in two lanthanide metal-organic frameworks with rich uncoordinated Lewis basic sites

CrystEngComm ◽  
2021 ◽  
Author(s):  
Liming Deng ◽  
Huihui Zhao ◽  
Kang Liu ◽  
Dingxuan Ma
Keyword(s):  
Environmental Contaminants ◽  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Basic Sites ◽  
Highly Sensitive ◽  
Metal Organic ◽  
Lanthanide Metal

Developing highly sensitive MOF-based probes for environmental contaminants detection is of much importance and challenging. Here, two new three-dimensional lanthanide metal-organic frameworks (Ln-MOFs), {[Eu(DTA)1.5(H2O)]·H2O}n (Eu-DTA) and [Tb(DTA)(C2O4)0.5(H2O)]n (Tb-DTA) (H2DTA =...

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