Characterization of LaCoO3 powders obtained by water-based sol–gel method with citric acid

2007 ◽  
Vol 27 (13-15) ◽  
pp. 4407-4411 ◽  
Author(s):  
Luminita Predoana ◽  
Barbara Malic ◽  
Marija Kosec ◽  
Mariana Carata ◽  
Monica Caldararu ◽  
...  
RSC Advances ◽  
2015 ◽  
Vol 5 (51) ◽  
pp. 40779-40784 ◽  
Author(s):  
Daochuan Jiang ◽  
Li Zhao ◽  
Yanbin Shao ◽  
Dianlong Wang

LiNi0.9Co0.05Mn0.025Mg0.025O2 prepared by sol–gel method using citric acid had a well ordered hexagonal layered structure and showed excellent electrochemical performance.


2009 ◽  
Vol 98 (2) ◽  
pp. 361-366 ◽  
Author(s):  
Luminita Predoana ◽  
Barbara Malic ◽  
Maria Zaharescu

2001 ◽  
Vol 97-98 ◽  
pp. 443-446 ◽  
Author(s):  
B.J. Hwang ◽  
R. Santhanam ◽  
D.G. Liu

2009 ◽  
Vol 3 (1-2) ◽  
pp. 39-42 ◽  
Author(s):  
Luminita Predoana ◽  
Barbara Malic ◽  
Marija Kosec ◽  
Mariana Scurtu ◽  
Monica Caldararu ◽  
...  

In the present work the LaCoO3 formation from gel precursors obtained by water-based sol-gel method with citric acid was studied. As precursors La and Co nitrates were used. The obtained gels were analyzed by TG/ DTA and TG/EGA. The decomposition of the gels takes place in two main steps with the evolution of the same volatile compounds (H2O, CO2 and NO2) leading to the conclusion that two types of bonding of the components in the gels occurred. The decomposition of the gels takes place up to 400?C. The gels thermally treated at 600?C lead to single pure perovskite rhombohedral phase of lanthanum cobalt oxide (LaCoO3). Some electrical properties of LaCoO3 measured in 'operando' conditions, i.e. in gas flow, at atmospheric pressure (by using the differential step technique DST) are presented and discussed.


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