Numerical analysis of wave propagating in a periodic layered structure

Controlling sound fields is a key technology for noise removal, acoustic lenses, energy harvesting, etc. This study investigated the control of sound field by a periodic layered structure. At first, we formulated the wave propagation in a periodic layered structure and proved that the wave fields constructed by the periodic boundary conditions are limited to plane wave modes with discretely different propagation directions. Numerical calculations clarified that the desired plane wave mode can be obtained in the transmitted wave through an intermediate thin-plate stacked region in a periodic layered structure, in which Lamb waves travel in each plate at different phase velocities and create phase difference at the exit of the intermediate thin-plate region. Further numerical investigations revealed that tuning frequency and length of the thin-plate region provides wave field more dominantly with a single wanted plane wave mode.

Two new bis(pyridine)-bis(amide)-based copper(II) coordination compounds for the electrochemical detection of trace Cr(VI) and efficient electrocatalytic oxygen evolution

Two new metal-organic compounds (MOCs) [Cu(L)0.5(3-nba)2] (1) and [Cu(L)(2,5-tdc)] (2) have been hydrothermally synthesized by employing the ligand N,N′-di(3-pyridyl)adipoamide (L) and two carboxylic acids (3-Hnba = 3-nitrobenzoic acid, 2,5-H2tdc = 2,5-thiophenedicarboxylic acid) as ligands. Compound 1 displays a metal-organic chain-like structure formed by the {Cu2(3-nba)4} double-paddle wheel units and the µ 2-bridging L ligands. The adjacent polymeric chains form a supramolecular layered structure through hydrogen bonding. Compound 2 shows a 3D metal-organic polymeric framework derived from Cu-L layers and µ 2-bridging 2,5-tdc ligands, which presents a 3,5-connected {4.62}{4.66.83} topology. The electrochemical and electrocatalytic behavior of the two compounds has been studied in detail. Carbon paste working electrodes modified with compounds 1 and 2 can be used as highly selective sensors for detecting traces Cr(VI). Both electrodes show also electrocatalytic performance in oxygen evolution reactions (OERs).

Broadband reflectors with a disordered layered structure: statistical properties of high performing configurations selected via genetic algorithm

Disordered multilayers consisting of alternating layers of two lossless dielectric materials with random thicknesses can behave as good reflectors in wide wavelength ranges except for narrow bands where the transmittance is significative. We use a dedicated genetic algorithm to select different configurations (thickness sequences) of such structures which exhibit very low transmittance in the entire visible wavelength range, showing that broadband disordered reflectors with very high performance can be designed. A statistical analysis of the thickness sequences selected by the genetic algorithm reveals that such sequences are characterized by correlated disorder and that the degree of autocorrelation is a key parameter in determining the reflection performance.

Optimization of structural expansion and contraction for TiS2 by controlling the electrochemical window of intercalation/delithiation

The reversible layered structure of TiS2 with relaxation, such as a spring, was obtained by controlling the optimized potential range of 0.9-2.8 V (vs. Li+/Li) to yield high discharge capacity,...

N-methylimidazolium containing metal phosphate-oxalates: solvent-free synthesis, crystal structure, and proton conduction

Two N-methylimidazolium containing metal phosphate-oxalates (denoted SCU-40 and SCU-42) were prepared under solvent-free conditions. SCU-40 has a three-dimensional structure with a zeolitic crb topology, while SCU-42 has a layered structure...