The first water-soluble tetraphosphorus ruthenium complex. Synthesis, characterization and kinetic study of its hydrolysis

2012 ◽  
Vol 714 ◽  
pp. 67-73 ◽  
Author(s):  
Maria Caporali ◽  
Luca Gonsalvi ◽  
Rustam Kagirov ◽  
Vincenzo Mirabello ◽  
Maurizio Peruzzini ◽  
...  
Keyword(s):  
Kinetic Study ◽  
Ruthenium Complex ◽  
Water Soluble

Synthesis of a Water-Soluble Ruthenium Complex and Its Catalytic Activity for Acceptorless Alcohol Dehydrogenation in Aqueous Medium

Synlett ◽  
2018 ◽  
Vol 29 (12) ◽  
pp. 1644-1648 ◽  
Author(s):  
Senthilkumar Muthaiah ◽  
Anita Bhatia
Keyword(s):  
Catalytic Activity ◽  
Aqueous Medium ◽  
Ruthenium Complex ◽  
Water Soluble ◽  
Catalytic Cycle ◽  
Secondary Alcohols ◽  
Atom Economy ◽  
Hydrogen Acceptor ◽  
Alcohol Dehydrogenation ◽  
Acceptorless Alcohol Dehydrogenation

The synthesis of a ruthenium complex bearing a PN-chelating ligand is described. The complex, in the presence of KOH, enabled the synthesis of ketones from secondary alcohols in the absence of a hydrogen acceptor in aqueous medium. This synthetic protocol, which uses water as the medium, is green and has a high atom economy as it avoids the use of an acceptor and produces hydrogen as the sole ­byproduct. Mechanistic investigations revealed that the catalytic cycle involves a phosphine dissociative pathway.

Kinetic study of oxidation of paracetamol by water-soluble colloidal MnO2 in the presence of an anionic surfactant

2016 ◽  
Vol 294 (10) ◽  
pp. 1611-1622 ◽  
Author(s):  
Ajaya Kumar Singh ◽  
Neelam Sen ◽  
Som Kumar Chatterjee ◽  
Md. Abu Bin Hasan Susan
Keyword(s):  
Kinetic Study ◽  
Anionic Surfactant ◽  
Water Soluble ◽  
Colloidal Mno2

Kinetic Study on Huisgen Reaction Catalyzed by Copper(I): Triazol Formation from Water-Soluble Alkyne and Alkyl Azide

Heterocycles ◽  
2009 ◽  
Vol 78 (4) ◽  
pp. 983 ◽  
Author(s):  
Jun Nishimura ◽  
Yosuke Kasuga ◽  
Mamoru Ito ◽  
Wataru Onoda ◽  
Yosuke Nakamura ◽  
...  
Keyword(s):  
Kinetic Study ◽  
Water Soluble ◽  
Huisgen Reaction

Water-Soluble Cp Ruthenium Complex Containing 1,3,5-Triaza-7-phosphaadamantane and 8-Thiotheophylline Derivatives: Synthesis, Characterization, and Antiproliferative Activity

2011 ◽  
Vol 50 (3) ◽  
pp. 873-882 ◽  
Author(s):  
Lazhar Hajji ◽  
Cristobal Saraiba-Bello ◽  
Antonio Romerosa ◽  
Gaspar Segovia-Torrente ◽  
Manuel Serrano-Ruiz ◽  
...  
Keyword(s):  
Antiproliferative Activity ◽  
Ruthenium Complex ◽  
Water Soluble

A kinetic study of the oxidation of l-methionine by water soluble colloidal MnO2

2007 ◽  
Vol 285 (10) ◽  
pp. 1169-1173 ◽  
Author(s):  
Mohammad Ilyas ◽  
Maqsood Ahmad Malik ◽  
Zaheer Khan
Keyword(s):  
Kinetic Study ◽  
Water Soluble ◽  
Colloidal Mno2
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