Enone dyes as visible photoinitiator in radical polymerization: the influence of peripheral N-alkylated (hetero)aromatic amine group

2021 ◽  
pp. 113449
Author(s):  
Tanlong Xue ◽  
Boyuan Huang ◽  
Yang Li ◽  
Xin Li ◽  
Jun Nie ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Aromatic Amine ◽  
Amine Group

scholarly journals Cubane Cu4I4(phosphine)4 Complexes as New Co-initiator for Free Radical Photopolymerization: Towards Aromatic Amine-Free Systems

2021 ◽  
Author(s):  
Jacques Lalevée ◽  
Fatima Hammoud ◽  
Mahmoud Rahal ◽  
Julien Egly ◽  
Fabrice Morlet-Savary ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Aromatic Amine ◽  
Free Radical Polymerization ◽  
Copper Iodide ◽  
Free Radical Photopolymerization ◽  
Acrylate Monomers ◽  
First Time

The investigation of copper-iodide cubane derivatives as new co-initiators for the free radical polymerization (FRP) of acrylate monomers under mild irradiation conditions is described for the first time here. These...

Free-radical polymerization of monomer-polymer solutions initiated by a peroxide-tertiary aromatic amine system

2006 ◽  
Vol 48 (7) ◽  
pp. 707-711 ◽  
Author(s):  
I. A. Novakov ◽  
Ya. S. Vygodskii ◽  
M. A. Vaniev ◽  
T. V. Volkova ◽  
V. A. Lukasik ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Aromatic Amine ◽  
Polymer Solutions ◽  
Free Radical Polymerization ◽  
Amine System

scholarly journals 1-Deoxy-1-(N-methyl-4-fluorophenylamino)-D-arabino-hexulose

IUCrData ◽  
2018 ◽  
Vol 3 (3) ◽  
Author(s):  
Valeri V. Mossine ◽  
Charles L. Barnes ◽  
Thomas P. Mawhinney
Keyword(s):  
Aromatic Amine ◽  
Solid State Nmr ◽  
Crystal Packing ◽  
Carbohydrate Chain ◽  
Hirshfeld Surface ◽  
Amine Group ◽  
Keto Form ◽  
Compound C ◽  
Nmr Data ◽  
Dimensional Network

The title compound, C13H18FNO5, consists of D-fructose with an aromatic amine. The carbohydrate chain is in the acyclic keto form and has the zigzag conformation, while the solid-state NMR data suggests a conformational dimorphism at the aromatic amine group. The carbohydrate portion is involved in extensive O—H...O hydrogen bonding, which forms a two-dimensional network parallel to (001) and organized into fused homodromic ring patterns. The Hirshfeld surface fingerprint plots reveal a major contribution of the non-polar H...H and C...H interactions to the crystal packing forces.

Tertiary Aromatic Amine Accelerators with Molecular Weights Above 400

1972 ◽  
Vol 51 (2) ◽  
pp. 473-482 ◽  
Author(s):  
R.L. Bowen ◽  
H. Argentar
Keyword(s):  
Free Radical ◽  
Nitrogen Atom ◽  
Radical Polymerization ◽  
Aromatic Ring ◽  
Aromatic Amine ◽  
Aromatic Amines ◽  
Free Radical Polymerization ◽  
Molecular Weights ◽  
Rate Of Polymerization

With the proper ring substituents, tertiary aromatic amines with large substituents on the nitrogen atom can be effective accelerators in free radical polymerization. Resistance to discoloration appears to be primarily a function of the substituents on the aromatic ring of the amine, whereas the rate of polymerization is dependent on both the alkyl substituents on the ring and the groups attached to the nitrogen atom.

Excess enthalpies of some aromatic amine + benzene mixtures

1979 ◽  
Vol 76 ◽  
pp. 381-382 ◽  
Author(s):  
Inmaculada Velasco ◽  
Santos Otín ◽  
Celso Gutiérrez-Losa
Keyword(s):  
Aromatic Amine ◽  
Excess Enthalpies
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