Insight into acidity driven third phase formation of TBP in organic solutions by MD simulation

2017 ◽  
Vol 232 ◽  
pp. 1-8 ◽  
Author(s):  
Meena B. Singh ◽  
Sonal G. Nayak ◽  
Ankit D. Kanthe ◽  
Rituja B. Patil ◽  
Vilas G. Gaikar
Keyword(s):  
Phase Formation ◽  
Md Simulation ◽  
Third Phase ◽  
Third Phase Formation ◽  
Organic Solutions ◽  
Insight Into

Trends in small angle neutron scattering of actinide–trialkyl phosphate complexes: a molecular insight into third phase formation

RSC Advances ◽  
2016 ◽  
Vol 6 (95) ◽  
pp. 92905-92916 ◽  
Author(s):  
Aditi Chandrasekar ◽  
A. Suresh ◽  
N. Sivaraman ◽  
V. K. Aswal
Keyword(s):  
Metal Complexes ◽  
Phase Formation ◽  
Small Angle ◽  
Small Angle Neutron Scattering ◽  
Molecular Probe ◽  
Third Phase ◽  
Third Phase Formation ◽  
Aggregation Tendency ◽  
Insight Into ◽  
Trialkyl Phosphate

SANS as a molecular probe was used to investigate and quantify the aggregation tendency of metal complexes, facilitating the prediction of third phase formation.

SANS Study of Third Phase Formation in the Extraction of HCl by TBP Isomers inn‐Octane

2006 ◽  
Vol 41 (10) ◽  
pp. 2075-2095 ◽  
Author(s):  
R. Chiarizia ◽  
D. C. Stepinski ◽  
P. Thiyagarajan
Keyword(s):  
Phase Formation ◽  
Third Phase ◽  
Third Phase Formation

Hydrofluorocarbon Diluent for CMPO Without Third Phase Formation: Extraction of Uranium(VI) and Lanthanide(III) Ions

2021 ◽  
pp. 1-14
Author(s):  
Chihiro Tabata ◽  
Masahiko Nakase ◽  
Miki Harigai ◽  
Kenji Shirasaki ◽  
Ayaki Sunaga ◽  
...  
Keyword(s):  
Phase Formation ◽  
Third Phase ◽  
Third Phase Formation

Probing the absence of third phase formation during the extraction of trivalent metal ions in an ionic liquid medium

2019 ◽  
Vol 43 (13) ◽  
pp. 5099-5108 ◽  
Author(s):  
Ch. Venkateswara Rao ◽  
Alok Rout ◽  
K. A. Venkatesan
Keyword(s):  
Ionic Liquid ◽  
Phase Formation ◽  
Acid Extraction ◽  
Trivalent Metal ◽  
Third Phase ◽  
Third Phase Formation ◽  
Trivalent Metal Ions ◽  
Nitric Acid Extraction ◽  
Molecular Diluents ◽  
Ionic Liquid Medium

In contrast to molecular diluents, diglycolamide (T2EHDGA) and carbamoylmethyl-phosphine oxide (CMPO) extractants diluted in an ionic liquid diluent minimize aggregation upon nitric acid extraction and prevent third phase formation during the course of solvent extraction.

Aggregation and Protonation Phenomena in Third Phase Formation: An NMR Study of the Quaternary Malonamide/Dodecane/Nitric Acid/Water System

2001 ◽  
Vol 105 (13) ◽  
pp. 2551-2564 ◽  
Author(s):  
Lydie Lefrançois ◽  
Jean-Jacques Delpuech ◽  
Marc Hébrant ◽  
Jacques Chrisment ◽  
Christian Tondre
Keyword(s):  
Nitric Acid ◽  
Phase Formation ◽  
Water System ◽  
Acid Water ◽  
Third Phase ◽  
Nmr Study ◽  
Third Phase Formation
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