Group 10 metal complexes with a tetradentate thiosemicarbazonate ligand: Synthesis, crystal structures and computational insights into the catalysis for C–C coupling via Mizoroki-Heck reaction

2020 ◽  
Vol 1199 ◽  
pp. 126997 ◽  
Author(s):  
Jackelinne C. Lima ◽  
Rebecca D. Nascimento ◽  
Luana M. Vilarinho ◽  
Alice P. Borges ◽  
Leonardo H.F. Silva ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Crystal Structures ◽  
Heck Reaction ◽  
Ligand Synthesis ◽  
Group 10

scholarly journals Heteropentanuclear Oxalato-Bridgednd-4f (n=4, 5) Metal Complexes with NO Ligand: Synthesis, Crystal Structures, Aqueous Stability and Antiproliferative Activity

2015 ◽  
Vol 21 (39) ◽  
pp. 13703-13713 ◽  
Author(s):  
Paul-Steffen Kuhn ◽  
Laura Cremer ◽  
Anatolie Gavriluta ◽  
Katarina K. Jovanović ◽  
Lana Filipović ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Crystal Structures ◽  
Antiproliferative Activity ◽  
Ligand Synthesis

Metal Complexes with a New N4O3Amine Pendant-Armed Macrocyclic Ligand:  Synthesis, Characterization, Crystal Structures, and Fluorescence Studies

2003 ◽  
Vol 42 (21) ◽  
pp. 6768-6779 ◽  
Author(s):  
Manuel Vicente ◽  
Rufina Bastida ◽  
Carlos Lodeiro ◽  
Alejandro Macías ◽  
A. Jorge Parola ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Crystal Structures ◽  
Macrocyclic Ligand ◽  
Fluorescence Studies ◽  
Ligand Synthesis

scholarly journals Functionalised Terpyridines and Their Metal Complexes—Solid-State Interactions

Chemistry ◽  
2021 ◽  
Vol 3 (1) ◽  
pp. 199-227
Author(s):  
Young Hoon Lee ◽  
Jee Young Kim ◽  
Sotaro Kusumoto ◽  
Hitomi Ohmagari ◽  
Miki Hasegawa ◽  
...  
Keyword(s):  
Solid State ◽  
Metal Complexes ◽  
Crystal Structures ◽  
Weak Interactions ◽  
Dispersion Interactions ◽  
Derivatives Of

Analysis of the weak interactions within the crystal structures of 33 complexes of various 4′-aromatic derivatives of 2,2′:6′,2″-terpyridine (tpy) shows that interactions that exceed dispersion are dominated, as expected, by cation⋯anion contacts but are associated with both ligand–ligand and ligand–solvent contacts, sometimes multicentred, in generally complicated arrays, probably largely determined by dispersion interactions between stacked aromatic units. With V(V) as the coordinating cation, there is evidence that the polarisation of the ligand results in an interaction exceeding dispersion at a carbon bound to nitrogen with oxygen or fluorine, an interaction unseen in the structures of M(II) (M = Fe, Co, Ni, Cu, Zn, Ru and Cd) complexes, except when 1,2,3-trimethoxyphenyl substituents are present in the 4′-tpy.

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