Mn(II) and Cd(II) macrocyclic Schiff base complexes with a single pendant coordinating 2-pyridylmethyl arm: Synthesis, X-ray crystal structure and NMR studies
Ninety Cr(III) macrocyclic Schiff base complexes of the type [CrL_n^(1-10) X_2 ]X(Where X = Cl- or NO-3 or CH3COO- and = macrocyclic Schiff base ligands derived from condensation of trimesic acid or p-phthalic acid or squaric acid with different aliphatic diamines) have been synthesised and characterised by elemental analysis; molar conductance; electronic spectra; IR; magnetic moment and XPS i.e. X-ray Photoelectron spectra data. An octahedral geometry was established for them.
In the present study, three novel Cu(ii) Schiff base complexes were synthesized and characterized using infrared spectroscopy, elemental analysis, conductivity measurements and X-ray crystallography.