One-pot synthesis and structural characterization of a Tb(III) coordination polymer based on a tripodal Schiff base ligand adopting an exo-bridging coordination mode

Polyhedron ◽  
2015 ◽  
Vol 85 ◽  
pp. 76-82 ◽  
Author(s):  
Atsuko Masuya ◽  
Chikai Igarashi ◽  
Masatoshi Kanesato ◽  
Hitoshi Hoshino ◽  
Nobuhiko Iki
Keyword(s):  
Schiff Base ◽  
Coordination Polymer ◽  
Structural Characterization ◽  
Schiff Base Ligand ◽  
Coordination Mode ◽  
One Pot ◽  
One Pot Synthesis

scholarly journals Structural Characterization of Heterodinuclear ZnII-LnIII Complexes (Ln = Pr, Nd) with a Ring-Contracted H2valdien-Derived Schiff Base Ligand

2021 ◽  
Author(s):  
Shabana Noor ◽  
Richard Goddard ◽  
Fehmeeda Khatoon ◽  
Sarvendra Kumar ◽  
Rüdiger W. Seidel
Keyword(s):  
Molecular Structure ◽  
Schiff Base ◽  
Structural Characterization ◽  
Schiff Base Ligand ◽  
Crystal And Molecular Structure ◽  
X Ray ◽  
X Ray Crystallography ◽  
Imidazoline Ring

AbstractSynthesis and structural characterization of two heterodinuclear ZnII-LnIII complexes with the formula [ZnLn(HL)(µ-OAc)(NO3)2(H2O)x(MeOH)1-x]NO3 · n H2O · n MeOH [Ln = Pr (1), Nd (2)] and the crystal and molecular structure of [ZnNd(HL)(µ-OAc)(NO3)2(H2O)] [ZnNd(HL)(OAc)(NO3)2(H2O)](NO3)2 · n H2O · n MeOH (3) are reported. The asymmetrical compartmental ligand (E)-2-(1-(2-((2-hydroxy-3-methoxybenzylidene)amino)-ethyl)imidazolidin-2-yl)-6-methoxyphenol (H2L) is formed from N1,N3-bis(3-methoxysalicylidene)diethylenetriamine (H2valdien) through intramolecular aminal formation, resulting in a peripheral imidazoline ring. The structures of 1–3 were revealed by X-ray crystallography. The smaller ZnII ion occupies the inner N2O2 compartment of the ligand, whereas the larger and more oxophilic LnIII ions are found in the outer O2O2’ site. Graphic Abstract Synthesis and structural characterization of two heterodinuclear ZnII-LnIII complexes (Ln = Pr, Nd) bearing an asymmetrical compartmental ligand formed in situ from N1,N3-bis(3-methoxysalicylidene)diethylenetriamine (H2valdien) through intramolecular aminal formation are reported.

One-Pot Synthesis and Structural Characterization of Poly(alkoxysilane)s Catalyzed by Silver-Gold Complexes

2013 ◽  
Vol 13 (1) ◽  
pp. 702-705 ◽  
Author(s):  
Hyeonsook Cheong ◽  
Sung-Hee Roh ◽  
Myong-Shik Cho ◽  
Myoung-Hee Kim ◽  
Hee-Gweon Woo ◽  
...  
Keyword(s):  
Structural Characterization ◽  
Gold Complexes ◽  
One Pot ◽  
One Pot Synthesis

Synthesis and Structural Characterization of a Nickel(II) Complex with Unsymmetrical NNO-Donor Schiff Base Ligand

2011 ◽  
Vol 41 (7) ◽  
pp. 1032-1035 ◽  
Author(s):  
Kuheli Das ◽  
Chittaranjan Sinha ◽  
Amitabha Datta ◽  
Neerish Revaprasadu
Keyword(s):  
Schiff Base ◽  
Structural Characterization ◽  
Schiff Base Ligand

Synthesis and characterization of a novel dicyanamide-bridged Co(II) 1-D coordination polymer with a N 4 -donor Schiff base ligand

2017 ◽  
Vol 464 ◽  
pp. 65-73 ◽  
Author(s):  
Saikat Banerjee ◽  
Sattwick Halder ◽  
Paula Brandão ◽  
Carlos J. Gómez García ◽  
Samia Benmansour ◽  
...  
Keyword(s):  
Schiff Base ◽  
Coordination Polymer ◽  
Schiff Base Ligand ◽  
Synthesis And Characterization

scholarly journals Synthesis and Structural Characterization of Schiff Base Ligand and their Metal Complexes

2015 ◽  
Vol 32 (2) ◽  
pp. 1249-1254 ◽  
Author(s):  
Amit Gautam ◽  
Arun Kumar ◽  
Kaushlendra Sharma ◽  
B. K Rai
Keyword(s):  
Schiff Base ◽  
Metal Complexes ◽  
Structural Characterization ◽  
Schiff Base Ligand
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