Synthesis and characterization of heteroscorpionate-based manganese carbonyl complexes as CO-releasing molecules

Tetrahedron ◽  
2015 ◽  
Vol 71 (19) ◽  
pp. 2951-2954 ◽  
Author(s):  
Frank Strinitz ◽  
Philipp Trautner ◽  
Hendrik Pfeiffer ◽  
Ulrich Schatzschneider ◽  
Nicolai Burzlaff
Keyword(s):  
Synthesis And Characterization ◽  
Carbonyl Complexes ◽  
Manganese Carbonyl

Synthesis and characterization of manganese complexes of the dibenzophospholyl ligand

2001 ◽  
Vol 79 (9) ◽  
pp. 1321-1329 ◽  
Author(s):  
Andreas Decken ◽  
Melanie A Neil ◽  
Frank Bottomley
Keyword(s):  
Mass Spectrometry ◽  
Ir Spectroscopy ◽  
Phosphorus Atom ◽  
Manganese Complexes ◽  
Synthesis And Characterization ◽  
Carbonyl Complexes ◽  
X Ray ◽  
Manganese Carbonyl

Manganese carbonyl complexes bearing dibenzophospholyl (DBP) and 1-phenyldibenzophosphole (Ph-DBP) ligands have been prepared. Reaction of Li-DBP with Mn(CO)5Br gave (µ2-DBP)(µ2-Br)Mn2(CO)8, while reaction of bis(1,1'-dibenzophospholyl) and Mn2(CO)10 yielded (µ2-DBP)2Mn2(CO)8. The phosphine adducts (Ph-DBP)Mn2(CO)9 and (Ph-DBP)2Mn2(CO)8 were obtained by reaction of Ph-DBP and Mn2(CO)10. The ligands are σ-bonded through the phosphorus atom in all complexes. The compounds were characterized by 1H, 13C, and 31P NMR and IR spectroscopy, mass spectrometry, and X-ray diffraction.Key words: dibenzophospholyl, dibenzophosphole, manganese, heterocycle.

Synthesis and characterization of μ4-S-containing double- and triple-butterfly iron carbonyl complexes.

2003 ◽  
Vol 346 ◽  
pp. 12-18 ◽  
Author(s):  
Li-Cheng Song ◽  
Qing-Mei Hu ◽  
Bao-Wei Sun ◽  
Ming-Yi Tang ◽  
Guo-Liang Lu
Keyword(s):  
Iron Carbonyl ◽  
Synthesis And Characterization ◽  
Carbonyl Complexes

Synthesis and Characterization of Manganese(I) Carbonyl Complexes of the Type [(OC)4Mn{μ-P(R)Aryl}]2

2016 ◽  
Vol 642 (6) ◽  
pp. 508-514
Author(s):  
Ralf Mede ◽  
Sascha Blohm ◽  
Helmar Görls ◽  
Matthias Westerhausen
Keyword(s):  
Synthesis And Characterization ◽  
Carbonyl Complexes

scholarly journals Synthesis and Characterization of Bidentate Isonitrile Iron Complexes

2021 ◽  
Author(s):  
Marion Till ◽  
John A. Kelly ◽  
Christoph G. P. Ziegler ◽  
Robert Wolf ◽  
Tianao Guo ◽  
...  
Keyword(s):  
New Species ◽  
Ir Spectroscopy ◽  
Iron Complexes ◽  
Molecular Structures ◽  
Synthesis And Characterization ◽  
Carbonyl Complexes ◽  
Subsequent Reduction ◽  
X Ray ◽  
X Ray Crystallography

Divalent iron complexes trans-[FeBr2(BINC)2], [Cp*FeCl(BINC)] (Cp* = Me5C5) and [FeBr2(CNAr3NC)2] with chelat-ing bis(isonitrile) ligands BINC (bis(2-isocyanophenyl)phenylphosphonate) and CNAr3NC (2,2’’-diisocyano-3,5,3’’,5’’tetramethyl-1,1’:3’,1’’-terphenyl) have been prepared and characterized. Their subsequent reduction yields di- and trinuclear compounds [Fe3(BINC)6], [Cp*Fe(BINC)]2, [Fe(CNAr3NC)2]2 and [K(Et2O)]2[Fe(CNAr3NC)2]2. The molecular structures of all new species were determined by X-ray crystallography. The molecular structures are compared to related iron carbonyl complexes. The complexes were further characterized by NMR and IR spectroscopy, and the electrochemical properties of selected compounds were analyzed by UV-Vis-NIR spectroelectrochemistry. <br>

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