Studies on the ɑ-lithiation-in situ intramolecular nucleophilic addition reactions of 2-acyl-N-sulfonylpyrroles

ChemInform Abstract: Recent Applications of α-Amido Sulfones as in situ Equivalents of Activated Imines for Asymmetric Catalytic Nucleophilic Addition Reactions

ChemInform ◽

10.1002/chin.201106245 ◽

2011 ◽

Vol 42 (6) ◽

pp. no-no

Author(s):

Biaolin Yin ◽

Yuanxiu Zhang ◽

Li-Wen Xu

Keyword(s):

Nucleophilic Addition ◽

Addition Reactions ◽

Asymmetric Catalytic

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IR and NMR Reaction Monitoring Techniques for Nucleophilic Addition Reactions: In Situ Monitoring of the Addition of Benzimidazole to a Pyridinium Salt

Organic Process Research & Development ◽

10.1021/acs.oprd.5b00029 ◽

2015 ◽

Vol 19 (9) ◽

pp. 1119-1127 ◽

Cited By ~ 12

Author(s):

Michele T. Drexler ◽

David A. Foley ◽

Howard W. Ward ◽

Hugh J. Clarke

Keyword(s):

Nucleophilic Addition ◽

Pyridinium Salt ◽

In Situ Monitoring ◽

Addition Reactions ◽

Reaction Monitoring ◽

Monitoring Techniques

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Recent Applications of α-Amido Sulfones as in situ Equivalents of Activated Imines for Asymmetric Catalytic Nucleophilic Addition Reactions

Synthesis ◽

10.1055/s-0030-1258241 ◽

2010 ◽

Vol 2010 (21) ◽

pp. 3583-3595 ◽

Cited By ~ 66

Author(s):

Biaolin Yin ◽

Li-Wen Xu ◽

Yuanxiu Zhang

Keyword(s):

Nucleophilic Addition ◽

Addition Reactions ◽

Asymmetric Catalytic

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Regioselective Functionalization of N-Fused Heteroaromatics via FeCl3-Catalyzed Nucleophilic Addition to Activated N-Heterocycles

Synthesis ◽

10.1055/s-0040-1705985 ◽

2020 ◽

Author(s):

Ikyon Kim ◽

Sung June Kim ◽

Sunhee Lee

Keyword(s):

Aromatic Compounds ◽

Nucleophilic Addition ◽

Chemical Space ◽

Wide Range ◽

Regioselective Functionalization

AbstractBroadening of nitrogen-fused heteroaromatic chemical space such as indolizine and pyrrolo[1,2-a]pyrazine was achieved via FeCl3-catalyzed nucleophilic addition of these N-fused aromatic compounds to a wide range of azolinium systems generated in situ, leading to novel N-fused heteroaromatic scaffolds with dearomatized N-heterocyclic substituents regioselectively. Nucleophilic addition of indolizines and pyrrolo[1,2-a]pyrazines mainly occurred at the C1 position of the isoquinoliniums and at the C4 site of the quinoliniums.

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Tricarbonyl(pyridine)chromium complexes: conversion into tricarbonyl(dihydropyridine)chromium complexes via regio- and stereo-selective nucleophilic addition reactions

Journal of the Chemical Society Perkin Transactions 1 ◽

10.1039/p19910000757 ◽

1991 ◽

pp. 757 ◽

Cited By ~ 10

Author(s):

Stephen G. Davies ◽

Mark R. Shipton

Keyword(s):

Nucleophilic Addition ◽

Addition Reactions ◽

Chromium Complexes

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Nucleophilic Addition Reactions of Nitriles to Nitrones under Mild Silylation Conditions

Synlett ◽

10.1055/s-0034-1378274 ◽

2014 ◽

Vol 25 (13) ◽

pp. 1863-1868 ◽

Cited By ~ 9

Author(s):

Fumihiko Yoshimura ◽

Keiji Tanino ◽

Taiki Abe

Keyword(s):

Nucleophilic Addition ◽

Addition Reactions

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Triflic Acid-Catalyzed Synthesis of Indole-Substituted Indane Derivatives via In Situ Formed Acetal-Facilitated Nucleophilic Addition and 4π-Electron-5-Carbon Electrocyclization Sequence

The Journal of Organic Chemistry ◽

10.1021/acs.joc.1c01396 ◽

2021 ◽

Author(s):

Golla Ramesh ◽

Rengarajan Balamurugan

Keyword(s):

Nucleophilic Addition ◽

Triflic Acid ◽

Acid Catalyzed

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Amide-Directed Reactions of Small Carbocycles

Current Organic Chemistry ◽

10.2174/1385272825666210706124215 ◽

2021 ◽

Vol 25 ◽

Author(s):

Pavel M. Yamanushkin ◽

Marina Rubina ◽

Michael Rubin

Keyword(s):

Transition Metal ◽

Transition Metals ◽

Nucleophilic Addition ◽

Addition Reactions ◽

Transition Metal Catalyzed ◽

Metal Catalyzed

: The topic of this review is the amide-directed functionalization of strained carbocycles — specifically, unsaturated or saturated three- and four-membered rings. The following approaches are discussed: a) directed carbometallation and hydrometallation of cyclopropenes catalyzed by transition metals; b) directed metal-templated nucleophilic addition reactions; c) directed C-H functionalization, including transition metal-catalyzed C-H-activation reactions; and d) directed radical additions.

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