Analysis of the products from the electrochemical fluorination of octanoyl chloride

The heightened activity of compounds containing fluorine, especially in the field of pharmaceuticals, provides major impetus for the development of new fluorination procedures. A scalable, versatile, and safe electrochemical fluorination...

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The electrochemical fluorination of propene

Journal of Applied Electrochemistry ◽

10.1007/bf01058866 ◽

1976 ◽

Vol 6 (1) ◽

pp. 23-32 ◽

Cited By ~ 7

Author(s):

F. G. Drakesmith ◽

D. A. Hughes

Keyword(s):

Electrochemical Fluorination

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ChemInform Abstract: STUDIES ON THE CYCLIZATION UPON ELECTROCHEMICAL FLUORINATION. II. THE ELECTROCHEMICAL FLUORINATION OF ALIPHATIC PRIMARY MONOHYDRIC ALCOHOLS AND ALDEHYDES

Chemischer Informationsdienst ◽

10.1002/chin.197642084 ◽

1976 ◽

Vol 7 (42) ◽

pp. no-no

Author(s):

TAKASHI ABE ◽

SHUNJI NAGASE ◽

HAJIME BABA

Keyword(s):

Electrochemical Fluorination ◽

Monohydric Alcohols

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Electrochemical Fluorination Reactions in Continuous Flow Using (Difluoroiodo)arene Mediators

Synfacts ◽

10.1055/s-0040-1720793 ◽

2021 ◽

Vol 17 (09) ◽

pp. 1067

Keyword(s):

Continuous Flow ◽

Electrochemical Fluorination

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Highly selective electrochemical fluorination of dithioacetal derivatives bearing electron-withdrawing substituents at the position α to the sulfur atom using poly(HF) salts

Beilstein Journal of Organic Chemistry ◽

10.3762/bjoc.11.12 ◽

2015 ◽

Vol 11 ◽

pp. 85-91 ◽

Cited By ~ 14

Author(s):

Bin Yin ◽

Shinsuke Inagi ◽

Toshio Fuchigami

Keyword(s):

Sulfur Atom ◽

Nitrile Group ◽

Amide Group ◽

Sharp Contrast ◽

Product Selectivity ◽

Electrochemical Fluorination ◽

Weak Electron ◽

Electron Withdrawing Substituents

Anodic fluorination of dithioacetals bearing electron-withdrawing ester, acetyl, amide, and nitrile groups at their α-positions was comparatively studied using various supporting poly(HF) salts like Et3N·nHF (n = 3–5) and Et4NF·nHF (n = 3–5). In the former two cases, the corresponding α-fluorination products or fluorodesulfurization products were obtained selectively depending on supporting poly(HF) salts used. In sharp contrast, in the latter two cases, fluorination product selectivity was strongly affected by the electron-withdrawing ability of α-substituents: A dithioacetal bearing a relatively weak electron-withdrawing amide group provided a fluorodesulfurization product selectively while a dithioacetal having a strongly electron-withdrawing nitrile group gave the α-fluorination product predominantly regardless of the poly(HF) salts used.

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