Organometallic conformational equilibria VII. On the planar rotation of π-allyl ligands in metal complexes

1969 ◽  
Vol 19 (1) ◽  
pp. P13-P16 ◽  
Author(s):  
J.W. Faller ◽  
M.J. Incorvia
Keyword(s):  
Metal Complexes ◽  
Conformational Equilibria ◽  
Planar Rotation ◽  
Allyl Ligands

The Sulfur–Fluorine Gauche Effect in Coinage-Metal Complexes: Augmenting Conformational Equilibria by Complexation

2016 ◽  
Vol 35 (17) ◽  
pp. 3040-3044 ◽  
Author(s):  
Nico Santschi ◽  
Christian Thiehoff ◽  
Mareike C. Holland ◽  
Constantin G. Daniliuc ◽  
K. N. Houk ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Coinage Metal ◽  
Gauche Effect ◽  
Conformational Equilibria

Alkali Metal Complexes of Silyl-Substitutedansa-(Tris)allyl Ligands: Metal-, Co-Ligand- and Substituent-Dependent Stereochemistry

2009 ◽  
Vol 2009 (27) ◽  
pp. 4157-4167 ◽  
Author(s):  
Scott A. Sulway ◽  
Roman Girshfeld ◽  
Sophia A. Solomon ◽  
Christopher A. Muryn ◽  
Jordi Poater ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Metal Complexes ◽  
Alkali Metal Complexes ◽  
Allyl Ligands

Mechanochemical changes on cyclometalated Ir(iii) acyclic carbene complexes – design and tuning of luminescent mechanochromic transition metal complexes

2020 ◽  
Vol 7 (3) ◽  
pp. 786-794 ◽  
Author(s):  
Jingqi Han ◽  
Kin-Man Tang ◽  
Shun-Cheung Cheng ◽  
Chi-On Ng ◽  
Yuen-Kiu Chun ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Carbene Complexes ◽  
New Class

A new class of luminescent cyclometalated Ir(iii) complexes with readily tunable mechanochromic properties derived from the mechanically induced trans-to-cis isomerization have been developed.

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