Insertion reactions of carbon dioxide and carbon disulfide into alkyl-copper bonds of alkylcopper(I) Complexes having tertiary Phosphine ligands

1976 ◽  
Vol 113 (2) ◽  
pp. 187-199 ◽  
Author(s):  
Akira Miyasuta ◽  
Akio Yamamoto
Keyword(s):  
Carbon Dioxide ◽  
Carbon Disulfide ◽  
Phosphine Ligands ◽  
Insertion Reactions ◽  
Tertiary Phosphine

Chemistry and catalytic properties of oxidized rhodium chlorocarbonyl complexes, Rh4Cl4(CO)4(O2)2P2; P = tertiary phosphine ligands

1978 ◽  
Vol 56 (15) ◽  
pp. 1965-1969 ◽  
Author(s):  
William R. Cullen ◽  
Brian R. James ◽  
Giorgio Stukul
Keyword(s):  
Carbon Dioxide ◽  
Carbon Monoxide ◽  
Catalytic Hydrogenation ◽  
Catalytic Properties ◽  
Phosphine Ligands ◽  
Carbon Dioxide Evolution ◽  
Tertiary Phosphine ◽  
Tetranuclear Complexes

The reactions of the title complexes Rh4Cl4(CO)4(O2)2P2 (where P is a tertiary phosphine type ligand, in particular diphenylisobutylphosphinite) with both dihydrogen and carbon monoxide were studied in solution in the absence and presence of excess P. The reaction stoichiometries, particularly a measured carbon dioxide evolution, confirm the formulation of the reactant tetranuclear complexes. The complexes are effective for catalytic hydrogenation and hydroformylation of olefinic substrates, and the nature of the active catalysts is considered.

Reactions of Carbon Disulfide and Carbon Dioxide Adducts (eta5-C5H5)(CO) 2Fe-CX2 with Organoiron Electrophiles

1988 ◽  
Author(s):  
Mary E. Giuseppetti ◽  
Bruce E. Landrum ◽  
John L. Shibley ◽  
Alan R. Cutler
Keyword(s):  
Carbon Dioxide ◽  
Carbon Disulfide
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