Free radical addition reactions—IV

Tetrahedron ◽  
1965 ◽  
Vol 21 (10) ◽  
pp. 2743-2747 ◽  
Author(s):  
H. Goldwhite ◽  
M.S. Gibson ◽  
C. Harris
Keyword(s):  
Free Radical ◽  
Radical Addition ◽  
Addition Reactions ◽  
Free Radical Addition

ChemInform Abstract: Free Radical Addition Reactions of Allylic Sulfones to Alkenes.

ChemInform ◽  
2010 ◽  
Vol 28 (38) ◽  
pp. no-no
Author(s):  
I. W. HARVEY ◽  
E. D. PHILLIPS ◽  
G. H. WHITHAM
Keyword(s):  
Free Radical ◽  
Radical Addition ◽  
Addition Reactions ◽  
Free Radical Addition

Markovnikov free radical addition reactions, a sleeping beauty kissed to life

2016 ◽  
Vol 45 (3) ◽  
pp. 577-583 ◽  
Author(s):  
Reinhard W. Hoffmann
Keyword(s):  
Free Radical ◽  
Double Bond ◽  
Hydrogen Atom ◽  
Sleeping Beauty ◽  
Radical Addition ◽  
Addition Reactions ◽  
Free Radical Addition

This review covers free radical additions, which are initiated by the formal addition of a hydrogen atom to a CC double bond.

Free radical addition reactions of allylic sulfones to alkenes

Tetrahedron ◽  
1997 ◽  
Vol 53 (18) ◽  
pp. 6493-6508 ◽  
Author(s):  
Iain W. Harvey ◽  
Eifion D. Phillips ◽  
Gordon H. Whitham
Keyword(s):  
Free Radical ◽  
Radical Addition ◽  
Addition Reactions ◽  
Free Radical Addition

PMO-treatment of the structure-reactivity relationships in free radical addition reactions of cycloalkenes

1981 ◽  
Vol 46 (10) ◽  
pp. 2524-2530 ◽  
Author(s):  
Robert Ponec ◽  
Milan Hájek ◽  
Jaroslav Málek
Keyword(s):  
Free Radical ◽  
Radical Addition ◽  
Addition Reactions ◽  
Perturbation Approach ◽  
Ring Strain ◽  
Free Radical Addition ◽  
Acceptable Agreement

The effect of ring strain in molecules of C5-C8 cycloalkenes and that of electronegativity of the attacking radicals upon reactivity of cycloalkenes in 1,2 addition reactions was studied by using a simple perturbation approach. The trends of the experimentally determined reactivities of cycloalkenes towards CH3, CCl3, CF2CF2CF3, CH3CO, NCCHCO2H5, C2H5, C2H5S and Br radicals were found to be in an acceptable agreement with the trends of the calculated Fukui's delocalisabilities Dr. The reactivity of cycloalkenes appears to be influenced by I-strain in the cycloalkene molecules as well as by electronegativity of the attacking radicals.

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