Facile synthesis of aryl(difluoromethyl)phosphonates through CuBr-mediated cross coupling reactions of [(diethoxyphosphinyl)difluoromethyl]zinc bromide with aryl iodides

Tetrahedron ◽  
1997 ◽  
Vol 53 (3) ◽  
pp. 815-822 ◽  
Author(s):  
Tsutomu Yokomatsu ◽  
Tetsuo Murano ◽  
Kenji Suemune ◽  
Shiroshi Shibuya
Keyword(s):  
Cross Coupling ◽  
Coupling Reactions ◽  
Facile Synthesis ◽  
Zinc Bromide ◽  
Cross Coupling Reactions ◽  
Aryl Iodides

scholarly journals Copper-Promoted Cross-Coupling Reactions for the Synthesis of Aryl(difluoromethyl)phosphonates Using Trimethylsilyl(difluoromethyl)phosphonate

Molecules ◽  
2018 ◽  
Vol 23 (12) ◽  
pp. 3292 ◽  
Author(s):  
Kazuki Komoda ◽  
Rei Iwamoto ◽  
Masakazu Kasumi ◽  
Hideki Amii
Keyword(s):  
Cross Coupling ◽  
Catalytic Amount ◽  
Coupling Reactions ◽  
Stoichiometric Amount ◽  
Cross Coupling Reactions ◽  
Aryl Iodides

A convenient and effective route for the synthesis of aryl(difluoromethyl)phosphonates has been developed based on cross-coupling reactions. Upon treatment with a stoichiometric amount (or a catalytic amount in some cases) of CuI and CsF, aryl iodides reacted smoothly with (silyldifluoromethyl)phosphonates to give the corresponding aryl(difluoromethyl)phosphonates in good yields.

scholarly journals Nickel-Catalyzed Negishi Cross-Coupling Reactions of Secondary Alkylzinc Halides and Aryl Iodides

2011 ◽  
Vol 13 (5) ◽  
pp. 1218-1221 ◽  
Author(s):  
Amruta Joshi-Pangu ◽  
Madhu Ganesh ◽  
Mark R. Biscoe
Keyword(s):  
Cross Coupling ◽  
Coupling Reactions ◽  
Cross Coupling Reactions ◽  
Aryl Iodides
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