scholarly journals The role of CuI in the siloxane-mediated Pd-catalyzed cross-coupling reactions of aryl iodides with aryl lithium reagents

Author(s):  
Yu Chen ◽  
Xiao Zhang ◽  
Fang Liu ◽  
Gucheng He ◽  
Ju Zhang ◽  
...  
Molecules ◽  
2018 ◽  
Vol 23 (12) ◽  
pp. 3292 ◽  
Author(s):  
Kazuki Komoda ◽  
Rei Iwamoto ◽  
Masakazu Kasumi ◽  
Hideki Amii

A convenient and effective route for the synthesis of aryl(difluoromethyl)phosphonates has been developed based on cross-coupling reactions. Upon treatment with a stoichiometric amount (or a catalytic amount in some cases) of CuI and CsF, aryl iodides reacted smoothly with (silyldifluoromethyl)phosphonates to give the corresponding aryl(difluoromethyl)phosphonates in good yields.


2011 ◽  
Vol 13 (5) ◽  
pp. 1218-1221 ◽  
Author(s):  
Amruta Joshi-Pangu ◽  
Madhu Ganesh ◽  
Mark R. Biscoe

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