Oxide-ion conductivity of the perovskite-type solid-solution system, (Ba1−x−ySrxLay)2In2O5+y

2002 ◽  
Vol 154-155 ◽  
pp. 571-576 ◽  
Author(s):  
K Kakinuma
2005 ◽  
Vol 242-244 ◽  
pp. 159-168 ◽  
Author(s):  
Katsuyoshi Kakinuma ◽  
Hiroshi Yamamura ◽  
Tooru Atake

We have discovered a high oxide ion conductor within the perovskite-type (Ba1-x-ySrxLay)InO2.5+y/2 solid-solution system. The system was derived from brownmillerite-type Ba2In2O5, which possessed a ordered oxide ion vacancies. When we doped La3+ into the Ba site, the vacancy changed to a disordered state. The oxide ion conductivity increased with the amount of doped La3+, reaching a maximum value of 0.12 (S/cm) at 800 oC in (Ba0.3Sr0.2La0.5)InO2.75, a level exceeding that of yttria-stabilized zirconia. The oxide ion conductivity of this system was strongly dependent on the unit cell free volume, which appears to be the key parameter governing oxide ion mobility.


1995 ◽  
Vol 30 (3) ◽  
pp. 307-316 ◽  
Author(s):  
In-Seon Kim ◽  
Woo-Hwan Jung ◽  
Yoshiyuki Inaguma ◽  
Tetsuro Nakamura ◽  
Mitsuru Itoh

ChemInform ◽  
2010 ◽  
Vol 26 (10) ◽  
pp. no-no
Author(s):  
T. ISHIHARA ◽  
H. MATSUDA ◽  
Y. TAKITA

1992 ◽  
Vol 53-56 ◽  
pp. 748-753 ◽  
Author(s):  
Y. Takeda ◽  
N. Imanishi ◽  
R. Kanno ◽  
T. Mizuno ◽  
H. Higuchi ◽  
...  

1999 ◽  
Vol 146 (5) ◽  
pp. 1643-1649 ◽  
Author(s):  
Tatsumi Ishihara ◽  
Haruyoshi Furutani ◽  
Hiroshi Arikawa ◽  
Miho Honda ◽  
Taner Akbay ◽  
...  

ChemInform ◽  
2010 ◽  
Vol 30 (30) ◽  
pp. no-no
Author(s):  
Tatsumi Ishihara ◽  
Haruyoshi Furutani ◽  
Hiroshi Arikawa ◽  
Miho Honda ◽  
Taner Akbay ◽  
...  

1996 ◽  
Vol 86-88 ◽  
pp. 197-201 ◽  
Author(s):  
Tatsumi Ishihara ◽  
Hideaki Matsuda ◽  
Mohamad Azmi bin Bustam ◽  
Yusaku Takita

1990 ◽  
Vol 87 (1) ◽  
pp. 245-249 ◽  
Author(s):  
Mitsuru Itoh ◽  
Tohru Sawada ◽  
Ruixing Liang ◽  
Hitoshi Kawaji ◽  
Tetsurō Nakamura

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