Electron paramagnetic resonance of gamma irradiated (CH3)3NHClO4 and CH3NH3ClO4 single crystals

1999 ◽  
Vol 54 (2) ◽  
pp. 143-149 ◽  
Author(s):  
Metin Yavuz ◽  
Fevzi Köksal
2005 ◽  
Vol 60 (7) ◽  
pp. 549-553 ◽  
Author(s):  
Şemsettin Osmanoğlua ◽  
Murat Aydın ◽  
M. Halim Başkana

The electron paramagnetic resonance spectra of γ -irradiated L-glutamine hydrochloride and N-carbamoyl- L-glutamic acid single crystals have been investigated at room temperature. Radiation damage centres are attributed to ĊH, ṄH2 and CH2Ċ(NH2)COOH radicals.


1975 ◽  
Vol 29b ◽  
pp. 475-482 ◽  
Author(s):  
Astrid Gräslund ◽  
Göran Löfroth ◽  
Anne-Charlotte Wiehager ◽  
S. Liaaen-Jensen ◽  
G. Schroll ◽  
...  

2004 ◽  
Vol 59 (10) ◽  
pp. 665-668 ◽  
Author(s):  
M. Halim Başkan ◽  
Şemsettin Osmanoğlu

Electron paramagnetic resonance of γ -irradiated single crystals of Nα -monochloroacetyl-α-aminoisobutyric acid were investigated at room temperature and 130 K. The paramagnetic center as attributed to the (CH3)2 ˙CCOOH radical.


1996 ◽  
Vol 51 (4) ◽  
pp. 245-248
Author(s):  
Geetha Jayaram ◽  
V. G. Krishnan

Abstract Electron Paramagnetic Resonance (EPR) studies have been carried out on the vanadyl (VO2) ion doped in single crystals of ZnTiF6 • 6H2O. The spectra indicate the presence of one set of eight lines characteristic of only one occupation site. The V-O bond orientation is along one of the three Zn-H2O bond directions in the trigonally distorted [Zn(H2O)6] octahedra. This behaviour is unlike that reported for vanadyl ion substituting for the M(H2O)6 sites in the Tutton salts, alums and AlCl3 • 6H2O. The Spin-Hamiltonian and bonding parameters for the [VO(H2O)5] complex have been evaluated. The hyperfine linewidths are 0.8 mT at 300 K and 77 K. No proton superhyperfine structure was observed at both these temperatures.


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