Anodic Depolarization of the Dropping Mercury Electrode in Sodium Nitrate-Potassium Nitrate Eutectic Melts Containing Solutions of Dissolved Alkali Metal Halides.

1965 ◽  
Vol 37 (12) ◽  
pp. 1513-1516 ◽  
Author(s):  
H. S. Swofford ◽  
C. L. Holifield
Keyword(s):  
Alkali Metal ◽  
Sodium Nitrate ◽  
Mercury Electrode ◽  
Potassium Nitrate ◽  
Metal Halides ◽  
Dropping Mercury Electrode ◽  
Alkali Metal Halides

Effect of Alkali Halides Upon Photocurrent Due to Emission of Electrons from Dropping Mercury Electrode Into Water

2002 ◽  
Vol 67 (4) ◽  
pp. 439-453 ◽  
Author(s):  
Teresa Cecchi ◽  
Paolo Passamonti ◽  
Filippo Pucciarelli
Keyword(s):  
Alkali Metal ◽  
Uv Light ◽  
Pure Water ◽  
Alkali Metal Cation ◽  
Mercury Electrode ◽  
Pure Hydrogen ◽  
Ultrapure Water ◽  
Metal Halides ◽  
Dropping Mercury Electrode ◽  
Alkali Metal Halides

When dropping mercury electrode (DME) dipped in ultrapure water, thoroughly deaerated with pure hydrogen, is irradiated with UV light, we can observe a cathodic photocurrent in the non-faradaic region of the polarographic curve, in the absence of scavengers of hydrated electrons. Newly we have followed the effect on photocurrent of initial very small additions of alkali metal chlorides to pure water. By repeated experiments, we could show that first additions of the alkali metal halides increase the photocurrent and that the already known suppression of photocurrent by addition of halides begins only after the halide concentration exceeds ca 10-4 mol l-1. We could show for the first time that in ultrapure water and dilute electrolyte solutions, the photocurrent follows a modified seven-halves law. The extent of the positive effect of small additions of alkali metal halides on photocurrent depends on the nature of each alkali metal cation. The reason for this specificity is discussed.

Halogenating and Nitrating Activity of Reagents Based on Sodium Nitrate and Alkali Metal Halides in Acetic Acid

2004 ◽  
Vol 40 (7) ◽  
pp. 917-923 ◽  
Author(s):  
V. D. Filimonov ◽  
Yu. Yu. Kulmanakova ◽  
M. S. Yusubov ◽  
I. A. Perederina ◽  
Ki-Whan Chi ◽  
...  
Keyword(s):  
Acetic Acid ◽  
Alkali Metal ◽  
Sodium Nitrate ◽  
Metal Halides ◽  
Alkali Metal Halides

Mechanochemical reactions of alkali metal-halides—The systems AX/BX/(H2O) with A, B = Na, K, Rb, Cs and X = Cl, Br, I

1990 ◽  
Vol 88 (2) ◽  
pp. 401-405 ◽  
Author(s):  
Ingrid Severin ◽  
Hans-J. Seifert ◽  
Shmuel Yariv
Keyword(s):  
Alkali Metal ◽  
Metal Halides ◽  
Alkali Metal Halides ◽  
Mechanochemical Reactions

Bending, Twisting, and Breaking CuCN Chains to Produce Framework Materials:  The Reactions of CuCN with Alkali-Metal Halides†

2004 ◽  
Vol 43 (25) ◽  
pp. 8040-8048 ◽  
Author(s):  
Ann M. Chippindale ◽  
Simon J. Hibble ◽  
Andrew R. Cowley
Keyword(s):  
Alkali Metal ◽  
Metal Halides ◽  
Framework Materials ◽  
Alkali Metal Halides

On Carbonate Ion Dissociation in Molten Alkali Metal Halides at ≈800 °C†

2003 ◽  
Vol 48 (3) ◽  
pp. 463-467 ◽  
Author(s):  
Victor L. Cherginets ◽  
Tatyana P. Rebrova
Keyword(s):  
Alkali Metal ◽  
Metal Halides ◽  
Ion Dissociation ◽  
Carbonate Ion ◽  
Alkali Metal Halides

scholarly journals Environmentally Benign Electrophilic Halogenation of Naphthalenes by H<sub>2</sub>O<sub>2</sub>—Alkali Metal Halides in An Aqueous Cationic Micellar Media

2012 ◽  
Vol 02 (03) ◽  
pp. 254-261 ◽  
Author(s):  
Kancharla Rajendar Reddy ◽  
Sariah Sana ◽  
Kusampally Uppalaiah ◽  
Kamatala Chinna Rajanna ◽  
Puppala Veerasomaiah
Keyword(s):  
Alkali Metal ◽  
Environmentally Benign ◽  
Micellar Media ◽  
Metal Halides ◽  
Alkali Metal Halides

Dissociative Phenomena in Triethylaluminum Complexes of Alkali Metal Halides and Pseudohalides

1982 ◽  
Vol 12 (1) ◽  
pp. 35-40
Author(s):  
James J. Harrison ◽  
David L. Beach
Keyword(s):  
Alkali Metal ◽  
Metal Halides ◽  
Alkali Metal Halides
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