The {Re4} Tetrahedral Cyanometalate Cluster Anion [{Re4(μ3-CCN)4}(CN)12]8– with Inner (μ3-CCN)3– Ligands and Its Features in Coordination of Cu2+ Cations

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A series of MOFs comprising tetrahedral lanthanide complexes, isonicotinate linkers, and the octahedral cluster anion [Re6S8(CN)6]4– demonstrate structure-directing effects of the rhenium cluster.


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