scholarly journals Diphosphinoboranes as Intramolecular Frustrated Lewis Pairs: P–B–P Bond Systems for the Activation of Dihydrogen, Carbon Dioxide, and Phenyl Isocyanate

2021 ◽  
Vol 60 (6) ◽  
pp. 3794-3806
Author(s):  
Natalia Szynkiewicz ◽  
Anna Ordyszewska ◽  
Jarosław Chojnacki ◽  
Rafał Grubba
Keyword(s):  
Carbon Dioxide ◽  
Phenyl Isocyanate ◽  
Frustrated Lewis Pairs ◽  
Lewis Pairs

Reactivity of bulky aminophosphanes towards small molecules: Activation of dihydrogen and carbon dioxide by aminophosphane/borane frustrated Lewis pairs

Polyhedron ◽  
2021 ◽  
Vol 194 ◽  
pp. 114930
Author(s):  
Magdalena Siedzielnik ◽  
Kinga Kaniewska-Laskowska ◽  
Natalia Szynkiewicz ◽  
Jarosław Chojnacki ◽  
Rafał Grubba
Keyword(s):  
Carbon Dioxide ◽  
Small Molecules ◽  
Frustrated Lewis Pairs ◽  
Lewis Pairs

scholarly journals Intramolecular B/N frustrated Lewis pairs and the hydrogenation of carbon dioxide

2015 ◽  
Vol 51 (48) ◽  
pp. 9797-9800 ◽  
Author(s):  
Marc-André Courtemanche ◽  
Alexander P. Pulis ◽  
Étienne Rochette ◽  
Marc-André Légaré ◽  
Douglas W. Stephan ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Frustrated Lewis Pairs ◽  
Hydrogenation Of Carbon Dioxide ◽  
Lewis Pairs

The FLP species 1-BR2-2-NMe2-C6H4 (R = 2,4,6-Me3C6H21, 2,4,5-Me3C6H22) reacts H2/CO2 to give formyl, acetal and methoxy-derivatives.

Cover Picture: Reversible Metal-Free Carbon Dioxide Binding by Frustrated Lewis Pairs (Angew. Chem. Int. Ed. 36/2009)

2009 ◽  
Vol 48 (36) ◽  
pp. 6563-6563
Author(s):  
Cornelia M. Mömming ◽  
Edwin Otten ◽  
Gerald Kehr ◽  
Roland Fröhlich ◽  
Stefan Grimme ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Free Carbon ◽  
Frustrated Lewis Pairs ◽  
Metal Free ◽  
Free Carbon Dioxide ◽  
Lewis Pairs

Activation of Carbon Dioxide by Silyl Triflate-Based Frustrated Lewis Pairs

2015 ◽  
Vol 21 (37) ◽  
pp. 13027-13034 ◽  
Author(s):  
Sarah A. Weicker ◽  
Douglas W. Stephan
Keyword(s):  
Carbon Dioxide ◽  
Frustrated Lewis Pairs ◽  
Lewis Pairs

A hydroboration route to geminal P/B frustrated Lewis pairs with a bulky secondary phosphane component and their reaction with carbon dioxide

2017 ◽  
Vol 46 (35) ◽  
pp. 11715-11721 ◽  
Author(s):  
Zhongbao Jian ◽  
Gerald Kehr ◽  
Constantin G. Daniliuc ◽  
Birgit Wibbeling ◽  
Gerhard Erker
Keyword(s):  
Carbon Dioxide ◽  
Frustrated Lewis Pairs ◽  
Frustrated Lewis Pair ◽  
Lewis Pairs

The hydroboration of a secondary alkynyl phosphane gives a geminal P/B frustrated Lewis pair that reacts with carbon dioxide.

scholarly journals Reversible Metal-Free Carbon Dioxide Binding by Frustrated Lewis Pairs

2009 ◽  
Vol 48 (36) ◽  
pp. 6643-6646 ◽  
Author(s):  
Cornelia M. Mömming ◽  
Edwin Otten ◽  
Gerald Kehr ◽  
Roland Fröhlich ◽  
Stefan Grimme ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Free Carbon ◽  
Frustrated Lewis Pairs ◽  
Metal Free ◽  
Free Carbon Dioxide ◽  
Lewis Pairs
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