Ca2[Ti(HPO4)2(PO4)]·H2O, Ca[Ti2(H2O)(HPO3)4]·H2O, and Ti(H2PO2)3: Solid-State Oxidation via Proton-Coupled Electron Transfer

2022 ◽  
Author(s):  
Ling-I Hung ◽  
Dai-Yi Hsieh ◽  
Tsung-Hsiu Hsieh ◽  
Pei-Lin Chen ◽  
Chia-Her Lin ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Solid State ◽  
Proton Coupled Electron Transfer

A Titanium(III) Phosphite Exhibits Polymorph-Distinct Redox Activity Involving Proton-Coupled Electron Transfer

2021 ◽  
Author(s):  
Ling-I Hung ◽  
Tsung-Hsiu Hsieh ◽  
Jhao-Yang Syu ◽  
Pei-Lin Chen ◽  
Chia-Her Lin ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Solid State ◽  
Redox Activity ◽  
Proton Distribution ◽  
Proton Coupled Electron Transfer

A novel titanium(III) phosphite with intriguing polymorphism and solid-state proton-coupled electron transfer (PCET) oxidation is presented. The polymorphs show structure-dependent PCET reactivity, interpretable by proton distribution in channels. Combined with...

scholarly journals Electron–Nuclear Dynamics Accompanying Proton-Coupled Electron Transfer

2021 ◽  
Vol 143 (8) ◽  
pp. 3104-3112
Author(s):  
Yusuke Yoneda ◽  
S. Jimena Mora ◽  
James Shee ◽  
Brian L. Wadsworth ◽  
Eric A. Arsenault ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Nuclear Dynamics ◽  
Proton Coupled Electron Transfer

Facile proton-coupled electron transfer enabled by coordination-induced E–H bond weakening to boron

2021 ◽  
Author(s):  
Anthony Wong ◽  
Arunavo Chakraborty ◽  
Deependra Bawari ◽  
Guang Wu ◽  
Roman Dobrovetsky ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Proton Coupled Electron Transfer

Coordination induced bond weakening (CIBW) leads to facile PCET at various E–H bonds.

Hydroarylation of Activated Alkenes Enabled by Proton-Coupled Electron Transfer

ACS Catalysis ◽  
2021 ◽  
pp. 4422-4429
Author(s):  
Zhaosheng Liu ◽  
Shuai Zhong ◽  
Xiaochen Ji ◽  
Guo-Jun Deng ◽  
Huawen Huang
Keyword(s):  
Electron Transfer ◽  
Proton Coupled Electron Transfer
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