Materialization of a Geometrically Frustrated Magnet in a Hybrid Coordination Framework: A Study of the Iron(II) Oxalate Fluoride Framework, KFe(C2O4)F

2019 ◽  
Vol 58 (18) ◽  
pp. 11971-11977 ◽  
Author(s):  
Katherine Tustain ◽  
Lewis Farrar ◽  
Wenjiao Yao ◽  
Philip Lightfoot ◽  
Ivan da Silva ◽  
...  
2018 ◽  
Vol 31 (11) ◽  
pp. 3553-3558 ◽  
Author(s):  
Yao Ying ◽  
Lichao Wang ◽  
Wangchang Li ◽  
Liang Qiao ◽  
Jingwu Zheng ◽  
...  

2010 ◽  
Vol 200 (3) ◽  
pp. 032047 ◽  
Author(s):  
Hiroki Morodomi ◽  
Koichiro Ienaga ◽  
Yuji Inagaki ◽  
Tatsuya Kawae ◽  
Masayuki Hagiwara ◽  
...  

2018 ◽  
Vol 18 (11) ◽  
pp. 1205-1211
Author(s):  
H. Huang ◽  
H. Jang ◽  
B.Y. Kang ◽  
B.K. Cho ◽  
C.-C. Kao ◽  
...  

2005 ◽  
Vol 74 (3) ◽  
pp. 863-866 ◽  
Author(s):  
Takehito Suzuki ◽  
Yuki Aikawa ◽  
Takuro Katsufuji

1995 ◽  
Vol 73 (11-12) ◽  
pp. 658-662 ◽  
Author(s):  
N. P. Raju ◽  
J. E. Greedan

Magnetic and powder neutron-diffraction studies were performed on a polycrystalline hexagonal compound β-NaCoPO4 with space group P65 and lattice constants, a = 10.167 Å and c = 23.785 Å (1Å = 10−10 m). The susceptibility data display a magnetic transition below about 3.2 K and follow the Curie–Weiss law in the temperature range 5–300 K with a paramagnetic Curie temperature, θp, of −16.6 K indicating that the spins are strongly frustrated. The Co2+ ions form a helix about the c direction but due to the topology of the structure the helix can be decomposed into sets of six roughly triangular layers per unit cell. Thus, nearest-neighbor antiferromagnetic interactions can give rise to frustration within the pseudolayers. Low-temperature neutron-diffraction data reveal magnetic Bragg peaks below the ordering temperature. A Rietveld refinement of the data suggests a 120° magnetic structure of Co2+ spins within each pseudolayer.


2013 ◽  
Vol 110 (1) ◽  
Author(s):  
A. D. LaForge ◽  
S. H. Pulido ◽  
R. J. Cava ◽  
B. C. Chan ◽  
A. P. Ramirez

Sign in / Sign up

Export Citation Format

Share Document