Diastereoselective Syntheses of (E)-α-Trialkylsilyl α,β-Unsaturated Esters, α-Silane-Substituted Conjugated Silyl Ketene Acetals, and α,γ-Substituted Allylsilanes

2018 ◽  
Vol 83 (17) ◽  
pp. 9914-9928 ◽  
Author(s):  
David A. Johnson ◽  
Amanda J. Mueller Hendrix ◽  
Michael P. Jennings
Keyword(s):  
Unsaturated Esters ◽  
Ketene Acetals ◽  
Silyl Ketene Acetals

scholarly journals Magnesium-catalyzed hydrosilylation of α,β-unsaturated esters

2015 ◽  
Vol 6 (12) ◽  
pp. 6901-6907 ◽  
Author(s):  
Nicole L. Lampland ◽  
Aradhana Pindwal ◽  
Steven R. Neal ◽  
Shealyn Schlauderaff ◽  
Arkady Ellern ◽  
...  
Keyword(s):  
Unsaturated Esters ◽  
Ketene Acetals ◽  
Silyl Ketene Acetals

A magnesium hydridoborate compound catalyzes the 1,4-hydrosilylation of α,β-unsaturated esters to give silyl ketene acetals.

Pd-Catalyzed γ-Arylation of α,β-Unsaturated Esters from Silyl Ketene Acetals

Synfacts ◽  
2010 ◽  
Vol 2010 (11) ◽  
pp. 1283-1283
Author(s):  
J. Hartwig ◽  
D. Huang
Keyword(s):  
Unsaturated Esters ◽  
Ketene Acetals ◽  
Silyl Ketene Acetals

Palladium-Catalyzed γ-Arylation of α,β-Unsaturated Esters from Silyl Ketene Acetals

2010 ◽  
Vol 122 (33) ◽  
pp. 5893-5897 ◽  
Author(s):  
David S. Huang ◽  
John F Hartwig
Keyword(s):  
Unsaturated Esters ◽  
Palladium Catalyzed ◽  
Ketene Acetals ◽  
Silyl Ketene Acetals
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