Diastereoselective Syntheses of (E)-α-Trialkylsilyl α,β-Unsaturated Esters, α-Silane-Substituted Conjugated Silyl Ketene Acetals, and α,γ-Substituted Allylsilanes

2018 ◽  
Vol 83 (17) ◽  
pp. 9914-9928 ◽  
Author(s):  
David A. Johnson ◽  
Amanda J. Mueller Hendrix ◽  
Michael P. Jennings
Keyword(s):  
Unsaturated Esters ◽  
Ketene Acetals ◽  
Silyl Ketene Acetals

scholarly journals Magnesium-catalyzed hydrosilylation of α,β-unsaturated esters

2015 ◽  
Vol 6 (12) ◽  
pp. 6901-6907 ◽  
Author(s):  
Nicole L. Lampland ◽  
Aradhana Pindwal ◽  
Steven R. Neal ◽  
Shealyn Schlauderaff ◽  
Arkady Ellern ◽  
...  
Keyword(s):  
Unsaturated Esters ◽  
Ketene Acetals ◽  
Silyl Ketene Acetals

A magnesium hydridoborate compound catalyzes the 1,4-hydrosilylation of α,β-unsaturated esters to give silyl ketene acetals.

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