Observation of π-Backbonding in a Boronyl-Coordinated Transition Metal Complex TaBO–

2020 ◽  
Vol 124 (48) ◽  
pp. 10001-10007
Author(s):  
Joseph Czekner ◽  
Lai-Sheng Wang
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Transition Metal Complex

A transition metal complex containing pyrazine-2,5-dicarboxylato bridging ligands: a novel three-dimensional manganese(II) compound

2003 ◽  
Vol 6 (9) ◽  
pp. 1224-1227 ◽  
Author(s):  
Garikoitz Beobide ◽  
Oscar Castillo ◽  
Antonio Luque ◽  
Urko Garcı́a-Couceiro ◽  
Juan P. Garcı́a-Teran ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Transition Metal Complex ◽  
Three Dimensional ◽  
Bridging Ligands

Two large ionic crystals: Both their anions and cations constructed by Anderson-type POM-supported transition metal complex

2011 ◽  
Vol 14 (2) ◽  
pp. 384-388 ◽  
Author(s):  
Rui–Kang Tan ◽  
Shu–Xia Liu ◽  
Wei Zhang ◽  
Shu–Jun Li ◽  
Yuan–Yuan Zhang
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Transition Metal Complex ◽  
Ionic Crystals ◽  
Anions And Cations

Transition Metal Complex Catalysed Photo- and Electrochemical (De)hydrogenations Involving C=O- and C=N-Bonds

Synthesis ◽  
2021 ◽  
Author(s):  
Igor Fokin ◽  
Kai-Thorben Kuessner ◽  
Inke Siewert
Keyword(s):  
Transition Metal ◽  
Metal Complex ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Transition Metal Complex ◽  
Basic Principles

Herein, we summarize the photo- and electrochemical protocols for dehydrogenation and hydrogenations involving carbonyl and imine functions. The three basic principles that have been explored to interconvert such moieties with transition metal complexes are discussed in detail and the substrate scope is evaluated. Furthermore, we describe some general thermodynamic and kinetic aspects of such electro- and photochemically driven reactions.

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