Synthesis of Bis(NHC)-Based CNC-Pincer Rare-Earth-Metal Amido Complexes and Their Application for the Hydrophosphination of Heterocumulenes

2015 ◽  
Vol 34 (18) ◽  
pp. 4553-4559 ◽  
Author(s):  
Xiaoxia Gu ◽  
Lijun Zhang ◽  
Xiancui Zhu ◽  
Shaowu Wang ◽  
Shuangliu Zhou ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Amido Complexes

CNC-Pincer Rare-Earth Metal Amido Complexes with a Diarylamido Linked Biscarbene Ligand: Synthesis, Characterization, and Catalytic Activity

2014 ◽  
Vol 33 (9) ◽  
pp. 2372-2379 ◽  
Author(s):  
Xiaoxia Gu ◽  
Xiancui Zhu ◽  
Yun Wei ◽  
Shaowu Wang ◽  
Shuangliu Zhou ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Amido Complexes ◽  
Ligand Synthesis

Highly Efficient Hydrophosphonylation of Aldehydes and Unactivated Ketones Catalyzed by Methylene-Linked Pyrrolyl Rare Earth Metal Amido Complexes

2012 ◽  
Vol 18 (9) ◽  
pp. 2653-2659 ◽  
Author(s):  
Shuangliu Zhou ◽  
Zhangshuan Wu ◽  
Jiewei Rong ◽  
Shaowu Wang ◽  
Gaosheng Yang ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Amido Complexes ◽  
Highly Efficient

Synthesis, structure, and catalytic activity of novel trinuclear rare-earth metal amido complexes incorporating μ–η5:η1bonding indolyl and μ3-oxo groups

2014 ◽  
Vol 43 (6) ◽  
pp. 2521-2533 ◽  
Author(s):  
Song Yang ◽  
Xiancui Zhu ◽  
Shuangliu Zhou ◽  
Shaowu Wang ◽  
Zhijun Feng ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Amido Complexes

ChemInform Abstract: Highly Efficient Hydrophosphonylation of Aldehydes and Unactivated Ketones Catalyzed by Methylene-Linked Pyrrolyl Rare Earth Metal Amido Complexes.

ChemInform ◽  
2012 ◽  
Vol 43 (29) ◽  
pp. no-no
Author(s):  
Shuangliu Zhou ◽  
Zhangshuan Wu ◽  
Jiewei Rong ◽  
Shaowu Wang ◽  
Gaosheng Yang ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Amido Complexes ◽  
Highly Efficient

Reactivity of functionalized indoles with rare-earth metal amides. Synthesis, characterization and catalytic activity of rare-earth metal complexes incorporating indolyl ligands

2015 ◽  
Vol 44 (47) ◽  
pp. 20502-20513 ◽  
Author(s):  
Zhijun Feng ◽  
Yun Wei ◽  
Shuangliu Zhou ◽  
Guangchao Zhang ◽  
Xiancui Zhu ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Rare Earth ◽  
Metal Complexes ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Amido Complexes ◽  
Metal Amides ◽  
Rare Earth Metal Complexes

The synthesized rare-earth metal amido complexes displayed different catalytic activity for intramolecular hydroamination of aminoalkenes.

Synthesis and characterization of 2-t-butylimino-functionalized indolyl rare-earth metal amido complexes for the catalytic addition of terminal alkynes to carbodiimides: the dimeric complexes with the alkynide species in the μ–η1:η2 bonding modes

2019 ◽  
Vol 48 (29) ◽  
pp. 11094-11102 ◽  
Author(s):  
Zhijun Feng ◽  
Zeming Huang ◽  
Shaowu Wang ◽  
Yun Wei ◽  
Shuangliu Zhou ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Catalytic Reaction ◽  
Earth Metal ◽  
Synthesis And Characterization ◽  
Terminal Alkynes ◽  
Amido Complexes ◽  
Dimeric Complexes ◽  
Catalytic Addition

Dimeric complexes [(μ–η1:η2-RCC)REL2]2 (L = 2-(tBuNCH)C8H5N), with alkynyl in the μ–η1:η2 modes, were isolated in the study of the catalytic reaction.

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