We report the synthesis and characterisation of new permethylpentalene zirconium bis(amido) and permethylpentalene zirconium cyclopentadienyl mono(amido) complexes, and their reactivity with carbon dioxide.
The bifunctional reactivity of three metal SNS (bis)amido complexes was computationally assessed by comparing the nucelophilicity of the nucelophilicity of the M–Namido donor (Mn, Fe, Co). Hirshfeld charges identified the...