Kinetically Controllable Pd-Catalyzed Decarboxylation Enabled [5 + 2] and [3 + 2] Cycloaddition toward Carbocycles Featuring Quaternary Carbons

2021 ◽  
Author(s):  
Biwei Yan ◽  
Linhong Zuo ◽  
Xiaowei Chang ◽  
Teng Liu ◽  
Manying Cui ◽  
...  
Keyword(s):  
Quaternary Carbons

ChemInform Abstract: Highly Diastereoselective Claisen Rearrangement Leading to Vicinal Quaternary Carbons Construction of Oxindoles.

ChemInform ◽  
2012 ◽  
Vol 43 (10) ◽  
pp. no-no
Author(s):  
Yumiko Matsuta ◽  
Takayuki Kobari ◽  
Sachiko Kurashima ◽  
Yuhsuke Kumakura ◽  
Masashi Shinada ◽  
...  
Keyword(s):  
Claisen Rearrangement ◽  
Quaternary Carbons

scholarly journals p-Menthane-3-carboxaldehyde: A Useful Chiral Auxiliary for the Synthesis of Chiral Quaternary Carbons of High Enantiomeric Purity.

ChemInform ◽  
2005 ◽  
Vol 36 (5) ◽  
Author(s):  
Claude Spino ◽  
Cedrickx Godbout ◽  
Christian Beaulieu ◽  
Magali Harter ◽  
Topwe M. Mwene-Mbeja ◽  
...  
Keyword(s):  
Enantiomeric Purity ◽  
Chiral Auxiliary ◽  
Quaternary Carbons

Formation of quaternary carbons through cobalt-catalyzed C(sp3)–C(sp3) Negishi cross-coupling

2020 ◽  
Vol 56 (59) ◽  
pp. 8210-8213 ◽  
Author(s):  
Eduardo Palao ◽  
Enol López ◽  
Iván Torres-Moya ◽  
Antonio de la Hoz ◽  
Ángel Díaz-Ortiz ◽  
...  
Keyword(s):  
Medicinal Chemistry ◽  
Cross Coupling ◽  
Quaternary Carbons

Formation of all-carbon-substituted quaternary carbons is a key challenge in organic and medicinal chemistry.

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