Considerations of the Effects of Naphthalene Moieties on the Design of Proton-Conductive Poly(arylene ether ketone) Membranes for Direct Methanol Fuel Cells

2016 ◽  
Vol 8 (36) ◽  
pp. 24079-24088 ◽  
Author(s):  
Baolong Wang ◽  
Lihua Hong ◽  
Yunfeng Li ◽  
Liang Zhao ◽  
Yuxue Wei ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Direct Methanol Fuel Cells ◽  
Arylene Ether ◽  
Direct Methanol ◽  
Ether Ketone ◽  
Methanol Fuel Cells

Chemically stable thioether cross-linked membranes derived from sulfonated poly(arylene ether ketone)s for direct methanol fuel cells

2017 ◽  
Vol 30 (2) ◽  
pp. 129-138 ◽  
Author(s):  
Ye Li ◽  
Bo Yang ◽  
Shilin Wei ◽  
Chengzhen Geng ◽  
Ming Kang ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Direct Methanol Fuel Cells ◽  
Methanol Permeability ◽  
Arylene Ether ◽  
Direct Methanol ◽  
Ether Ketone ◽  
Methanol Fuel Cells ◽  
Cross Linker ◽  
The Cross ◽  
Sulfonated Poly

A series of thioether cross-linked membranes based on sulfonated poly(arylene ether ketone)s containing propenyl groups were prepared to solve the problem of high methanol permeability for proton electrolyte membrane in direct methanol fuel cells (DMFCs). For this purpose, 4,4′-thiobisbenzenethiol was selected as cross-linker, and the cross-linked structure was formed via thiol-ene click chemical reaction between propenyl and thiol groups. Compared with pristine membrane, the thioether cross-linked membranes exhibited improved mechanical properties and dimensional stabilities. As the cross-linker increased, the swelling ratio decreased from 11.01% to 8.64% at 20°C and from 15.18% to 10.69% at 80°C. Furthermore, the modified membranes exhibited reduced methanol permeability coefficients (down to 4.03 × 10−7 cm2 s−1), which was nearly half of the pristine membrane (7.66 × 10−7 cm2 s−1). Due to the thioether units, the cross-linked membranes showed enhanced oxidative stabilities, and the longest elapsed time in Fenton’s reagent was 225 min, which was 2.5 times longer than that of pristine polymeric membrane. Although the proton conductivity decreased upon the addition of cross-linker agent, the selectivity value increased due to the lower methanol permeability. Thus, all the results implied that the thioether cross-linked membranes were promising alternative materials for DMFCs application.

Block sulfonated poly(arylene ether ketone) containing flexible side-chain groups for direct methanol fuel cells usage

2012 ◽  
Vol 417-418 ◽  
pp. 61-68 ◽  
Author(s):  
Tianyi Na ◽  
Ke Shao ◽  
Jing Zhu ◽  
Hongcheng Sun ◽  
Zhongguo Liu ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Direct Methanol Fuel Cells ◽  
Side Chain ◽  
Arylene Ether ◽  
Direct Methanol ◽  
Ether Ketone ◽  
Methanol Fuel Cells ◽  
Sulfonated Poly

Novel side-chain-type sulfonated poly(arylene ether ketone) with pendant sulfoalkyl groups for direct methanol fuel cells

Polymer ◽  
2009 ◽  
Vol 50 (19) ◽  
pp. 4471-4478 ◽  
Author(s):  
Yang Zhang ◽  
Ying Wan ◽  
Chengji Zhao ◽  
Ke Shao ◽  
Gang Zhang ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Direct Methanol Fuel Cells ◽  
Side Chain ◽  
Arylene Ether ◽  
Direct Methanol ◽  
Ether Ketone ◽  
Methanol Fuel Cells ◽  
Chain Type ◽  
Sulfonated Poly

Fluorinated naphthalene-based poly(arylene ether ketone)s containing pendant groups for direct methanol fuel cells

Polymer ◽  
2012 ◽  
Vol 53 (20) ◽  
pp. 4413-4419 ◽  
Author(s):  
Tianyi Na ◽  
Ke Shao ◽  
Jing Zhu ◽  
Zhongguo Liu ◽  
Hongcheng Sun ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Direct Methanol Fuel Cells ◽  
Arylene Ether ◽  
Direct Methanol ◽  
Ether Ketone ◽  
Methanol Fuel Cells

Organic-inorganic (polysiloxane) crosslinked sulphonated poly(ether ether ketone ketone) hybrid membranes for direct methanol fuel cells

2021 ◽  
Vol 363 ◽  
pp. 115596
Author(s):  
Alejandro Gutiérrez-Sánchez ◽  
Juan C. Ruíz-Segura ◽  
Ana L. Ocampo-Flores ◽  
Josefina de Gyves
Keyword(s):  
Fuel Cells ◽  
Direct Methanol Fuel Cells ◽  
Hybrid Membranes ◽  
Ether Ether Ketone ◽  
Poly Ether Ether Ketone ◽  
Direct Methanol ◽  
Ether Ketone ◽  
Methanol Fuel Cells

Sulfonated polyether ether ketone/strontium zirconite@TiO2 nanocomposite membranes for direct methanol fuel cells

2017 ◽  
Vol 5 (38) ◽  
pp. 20497-20504 ◽  
Author(s):  
G. Gnana kumar ◽  
Arumugam Manthiram
Keyword(s):  
Fuel Cells ◽  
Power Density ◽  
Direct Methanol Fuel Cells ◽  
Inorganic Filler ◽  
Nanocomposite Membranes ◽  
Polyether Ether Ketone ◽  
Sulfonated Polyether Ether Ketone ◽  
Direct Methanol ◽  
Ether Ketone ◽  
Methanol Fuel Cells

The use of SrZrO3@TiO2 nanocuboids as an inorganic filler in SPEEK membranes enhances their performance in DMFCs with a power density higher than that achieved with a Nafion 117 membrane.

Functionalized Single‐Walled Carbon Nanohorns to Reinforce Sulfonated Poly(ether ether ketone) Electrolyte for Direct Methanol Fuel Cells

2020 ◽  
Vol 7 (17) ◽  
pp. 3632-3636
Author(s):  
Parameswaran Turanelloormana ◽  
Sudeshna Sarmah ◽  
Arun Torris ◽  
Santoshkumar D. Bhat ◽  
Sreekuttan M. Unni
Keyword(s):  
Fuel Cells ◽  
Direct Methanol Fuel Cells ◽  
Carbon Nanohorns ◽  
Single Walled Carbon ◽  
Ether Ether Ketone ◽  
Poly Ether Ether Ketone ◽  
Direct Methanol ◽  
Ether Ketone ◽  
Methanol Fuel Cells ◽  
Sulfonated Poly
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