Obtaining Chain Length Dependent Termination Rate Coefficients via Thermally Initiated Reversible Addition Fragmentation Chain Transfer Experiments

2006 ◽  
pp. 486-500 ◽  
Author(s):  
Alexander Theis ◽  
Martina H. Stenzel ◽  
Thomas P. Davis ◽  
Christopher Barner-Kowollik
Keyword(s):  
Chain Length ◽  
Chain Transfer ◽  
Rate Coefficients ◽  
Termination Rate ◽  
Reversible Addition

Access to Chain Length Dependent Termination Rate Coefficients of Methyl Acrylate via Reversible Addition−Fragmentation Chain Transfer Polymerization

2005 ◽  
Vol 38 (7) ◽  
pp. 2595-2605 ◽  
Author(s):  
Alexander Theis ◽  
Achim Feldermann ◽  
Nathalie Charton ◽  
Martina H. Stenzel ◽  
Thomas P. Davis ◽  
...  
Keyword(s):  
Chain Length ◽  
Methyl Acrylate ◽  
Chain Transfer ◽  
Rate Coefficients ◽  
Termination Rate ◽  
Reversible Addition ◽  
Chain Transfer Polymerization

Accessing Chain Length Dependent Termination Rate Coefficients of Methyl Methacrylate (MMA) via the Reversible Addition Fragmentation Chain Transfer (RAFT) Process

2005 ◽  
Vol 206 (20) ◽  
pp. 2047-2053 ◽  
Author(s):  
Geoffrey Johnston-Hall ◽  
Alexander Theis ◽  
Michael J. Monteiro ◽  
Thomas P. Davis ◽  
Martina H. Stenzel ◽  
...  
Keyword(s):  
Methyl Methacrylate ◽  
Chain Length ◽  
Chain Transfer ◽  
Rate Coefficients ◽  
Termination Rate ◽  
Reversible Addition

Chain Length Dependent Termination Rate Coefficients of Methyl Methacrylate (MMA) in the Gel Regime:  Accessingkti,iUsing Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization

2007 ◽  
Vol 40 (8) ◽  
pp. 2730-2736 ◽  
Author(s):  
Geoffrey Johnston-Hall ◽  
Martina H. Stenzel ◽  
Thomas P. Davis ◽  
Christopher Barner-Kowollik ◽  
Michael J. Monteiro
Keyword(s):  
Methyl Methacrylate ◽  
Chain Length ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Rate Coefficients ◽  
Termination Rate ◽  
Reversible Addition

Accessing the Chain Length Dependence of the Termination Rate Coefficient for Disparate Length Radicals via Reversible Addition Fragmentation Chain Transfer Chemistry:  A Theoretical Study

2006 ◽  
Vol 39 (15) ◽  
pp. 4975-4982 ◽  
Author(s):  
Tara M. Lovestead ◽  
Alexander Theis ◽  
Thomas P. Davis ◽  
Martina H. Stenzel ◽  
Christopher Barner-Kowollik
Keyword(s):  
Chain Length ◽  
Chain Transfer ◽  
Theoretical Study ◽  
Rate Coefficient ◽  
Length Dependence ◽  
Termination Rate ◽  
Reversible Addition

scholarly journals Fundamentals of reversible addition–fragmentation chain transfer (RAFT)

2020 ◽  
Vol 0 (0) ◽  
Author(s):  
Catherine L. Moad ◽  
Graeme Moad
Keyword(s):  
Radical Polymerization ◽  
Chain Length ◽  
Molar Mass ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Length Distribution ◽  
Chain Length Distribution ◽  
Reversible Addition ◽  
Raft Agent ◽  
End Group

Abstract Radical polymerization is transformed into what is known as reversible addition–fragmentation chain transfer (RAFT) polymerization by the addition of a RAFT agent. RAFT polymerization enables the preparation of polymers with predictable molar mass, narrow chain length distribution, high end-group integrity and provides the ability to construct macromolecules with the intricate architectures and composition demanded by modern applications in medicine, electronics and nanotechnology. This paper provides a background to understanding the mechanism of RAFT polymerization and how this technique has evolved.

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