Jahn-Teller effect of titanium(3+) in octahedral coordination: a spectroscopic study of hexachlorotitanate (TiCl63-) complexes

1985 ◽  
Vol 24 (18) ◽  
pp. 2751-2754 ◽  
Author(s):  
R. Ameis ◽  
S. Kremer ◽  
D. Reinen
2006 ◽  
Vol 62 (5) ◽  
pp. m1018-m1020 ◽  
Author(s):  
Gang Zhu ◽  
Zong-Xun Tang

In the title compound, [Mn(C12H8N2)2(H2O)2][NbOF5], each of the MnII and NbV atoms has a distorted octahedral coordination. In the [NbOF5]2− anion, a characteristic short terminal Nb=O bond and a longer Nb—F bond are observed, which result in the out-of-center distortion of the octahedron, a manifestation of the second-order Jahn–Teller effect.


2009 ◽  
Vol 164 (2) ◽  
pp. 132-137
Author(s):  
Fevzi Köksal ◽  
Dilek Demir ◽  
Rahmi Köseoğlu

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