Heterometallic CoIII4FeIII2 Schiff Base Complex: Structure, Electron Paramagnetic Resonance, and Alkane Oxidation Catalytic Activity

2012 ◽  
Vol 51 (16) ◽  
pp. 9110-9122 ◽  
Author(s):  
Dmytro S. Nesterov ◽  
Eduard N. Chygorin ◽  
Volodymyr N. Kokozay ◽  
Volodymyr V. Bon ◽  
Roman Boča ◽  
...  
Keyword(s):  
Electron Paramagnetic Resonance ◽  
Schiff Base ◽  
Catalytic Activity ◽  
Complex Structure ◽  
Schiff Base Complex ◽  
Alkane Oxidation ◽  
Paramagnetic Resonance ◽  
Base Complex ◽  
Electron Paramagnetic

A polyhedral oligomeric silsesquioxane (POSS)-bridged oxo-molybdenum Schiff base complex with enhanced heterogeneous catalytic activity in epoxidation

2014 ◽  
Vol 4 (4) ◽  
pp. 997-1004 ◽  
Author(s):  
Yan Leng ◽  
Jian Liu ◽  
Chenjun Zhang ◽  
Pingping Jiang
Keyword(s):  
Schiff Base ◽  
Catalytic Activity ◽  
Polyhedral Oligomeric Silsesquioxane ◽  
Schiff Base Complex ◽  
Efficient Catalyst ◽  
Butyl Hydroperoxide ◽  
Base Complex ◽  
Heterogeneous Catalytic ◽  
Oligomeric Silsesquioxane ◽  
Epoxidation Of Alkenes

A novel POSS-bridged oxo-molybdenum Schiff base complex was demonstrated to be a highly efficient catalyst for epoxidation of alkenes with aqueous tert-butyl hydroperoxide.

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